2-[(2-methylthio)benzylideneamino]phenol | 906516-76-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-[(2-methylthio)benzylideneamino]phenol
• 英文别名: 2-[(2-methylthio)benzylideneimino]phenol；Hons；2-[(2-Methylsulfanylphenyl)methylideneamino]phenol
• CAS: 906516-76-5
• 化学式: C₁₄H₁₃NOS
• 分子量: 243.329
• InChiKey: IBMAISZHGKJYHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  57.9
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  五羰基溴铼(I) 、 2-[(2-methylthio)benzylideneamino]phenol 、 水 、 甲苯 以 甲苯 为溶剂， 以37%的产率得到fac-[Re(CO)3(2-[(2-methylthio)benzylideneimino]phenolato)(2-aminophenol)]*(toluene)
  参考文献：
  名称：

  Rhenium(I), (III) and (V) complexes of tridentate ONX (X=O, N, S)-donor Schiff bases

  摘要：

  The reactions of the potentially tridentate Schiff bases 2-[(2-hydroxyphenyl)iminomethyl]phenol (H(2)ono) and 2-(2-aminobenzylideneimino)phenol (H(3)onn) with trans-[ReOBr3(PPh3)(2)] were studied, and the complexes [(ReBr)-Br-III(PPh3)(2)(ono)] (1) and [(ReBr)-Br-V(PPh3)(2)(onn)]Br (2) were isolated. In 1 ono acts as a dianionic tridentate ligand, and in 2 onn is coordinated as a tridentate trianionic imido-imino-phenolate. The complex [Re-I(CO)(3)(ons)(Hno)] was isolated from the reaction of [Re(CO)(5)Br] with 2-[(2-methylthio)benzylideneimino]phenol (Moos; Moo = 2-aminophenol), with ons coordinated as a bidentate chelate with a free SCH3 group. These complexes were characterized by X-ray crystallography, NMR and IR spectroscopy. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.013
• 作为产物：
  描述：

  邻甲硫基苯甲醛 、 2-氨基苯酚 以 甲醇 为溶剂， 反应 1.0h， 以60%的产率得到2-[(2-methylthio)benzylideneamino]phenol
  参考文献：
  名称：

  Rhenium(I), (III) and (V) complexes of tridentate ONX (X=O, N, S)-donor Schiff bases

  摘要：

  The reactions of the potentially tridentate Schiff bases 2-[(2-hydroxyphenyl)iminomethyl]phenol (H(2)ono) and 2-(2-aminobenzylideneimino)phenol (H(3)onn) with trans-[ReOBr3(PPh3)(2)] were studied, and the complexes [(ReBr)-Br-III(PPh3)(2)(ono)] (1) and [(ReBr)-Br-V(PPh3)(2)(onn)]Br (2) were isolated. In 1 ono acts as a dianionic tridentate ligand, and in 2 onn is coordinated as a tridentate trianionic imido-imino-phenolate. The complex [Re-I(CO)(3)(ons)(Hno)] was isolated from the reaction of [Re(CO)(5)Br] with 2-[(2-methylthio)benzylideneimino]phenol (Moos; Moo = 2-aminophenol), with ons coordinated as a bidentate chelate with a free SCH3 group. These complexes were characterized by X-ray crystallography, NMR and IR spectroscopy. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.013

文献信息

• Rhenium(I), (III) and (V) complexes of tridentate ONX (X=O, N, S)-donor Schiff bases
  作者：P. Mayer、K.C. Potgieter、T.I.A. Gerber

  DOI：10.1016/j.poly.2010.01.013

  日期：2010.3

  The reactions of the potentially tridentate Schiff bases 2-[(2-hydroxyphenyl)iminomethyl]phenol (H(2)ono) and 2-(2-aminobenzylideneimino)phenol (H(3)onn) with trans-[ReOBr3(PPh3)(2)] were studied, and the complexes [(ReBr)-Br-III(PPh3)(2)(ono)] (1) and [(ReBr)-Br-V(PPh3)(2)(onn)]Br (2) were isolated. In 1 ono acts as a dianionic tridentate ligand, and in 2 onn is coordinated as a tridentate trianionic imido-imino-phenolate. The complex [Re-I(CO)(3)(ons)(Hno)] was isolated from the reaction of [Re(CO)(5)Br] with 2-[(2-methylthio)benzylideneimino]phenol (Moos; Moo = 2-aminophenol), with ons coordinated as a bidentate chelate with a free SCH3 group. These complexes were characterized by X-ray crystallography, NMR and IR spectroscopy. (C) 2010 Elsevier Ltd. All rights reserved.