2-diphenylphosphanyl-N-di(propan-2-yl)phosphanylethanamine | 508170-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-diphenylphosphanyl-N-di(propan-2-yl)phosphanylethanamine
• CAS: 508170-29-4
• 化学式: C₂₀H₂₉NP₂
• 分子量: 345.404
• InChiKey: LFHICEFIKRLPKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(benzonitrile)dichloroplatinum(II) 、 2-diphenylphosphanyl-N-di(propan-2-yl)phosphanylethanamine 以 二氯甲烷 为溶剂， 以75%的产率得到PtCl₂((C₆H₅)2P(CH₂)2NHP(CH(CH₃)2)2)
  参考文献：
  名称：

  Preparation and coordination chemistry of Ph2P(CH2)nNHPiPr2 (n=2, 3)

  摘要：

  Unsymmetrical diphosphine ligands of the type Ph2P(CH2)(n)NHPPr2i [n = 2 (1), 3 (2)] have been obtained by reacting the appropriate (diphenylphosphino)alkylamine, Ph2P(CH2)(n)NH2 with chlorodi-iso-propylphosphine, in the presence of triethylamine. Reaction of Ph2P(CH2)(2)NHPPr2i with PdCl2(PhCN)(2), PtCl2(PhCN)(2), PtMe2(cod) and PtClMe(cod), NiCl2.6H(2)O and Fe(CO)(2)(eta(5)-C5H5)I gives the corresponding chelate complexes, PdCl2L, PtX2L, NiCl2L and Fe(CO)(eta(5)-C5H5)L. Reaction of Ph2P(CH2)(3)NHPPr2i with PtCl2(PhCN)(2), PtMe2(cod) and PdCl2(PhCN)(2) yields the chelate complexes and reaction with PtClMe(cod) led to a 50:50 mixture of chelate isomers. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01236-6

文献信息

• Preparation and coordination chemistry of Ph2P(CH2)nNHPiPr2 (n=2, 3)
  作者：Tracey Appleby、Stephen M Aucott、Matthew L Clarke、Alexandra M.Z Slawin、J Derek Woollins

  DOI：10.1016/s0277-5387(02)01236-6

  日期：2002.12

  Unsymmetrical diphosphine ligands of the type Ph2P(CH2)(n)NHPPr2i [n = 2 (1), 3 (2)] have been obtained by reacting the appropriate (diphenylphosphino)alkylamine, Ph2P(CH2)(n)NH2 with chlorodi-iso-propylphosphine, in the presence of triethylamine. Reaction of Ph2P(CH2)(2)NHPPr2i with PdCl2(PhCN)(2), PtCl2(PhCN)(2), PtMe2(cod) and PtClMe(cod), NiCl2.6H(2)O and Fe(CO)(2)(eta(5)-C5H5)I gives the corresponding chelate complexes, PdCl2L, PtX2L, NiCl2L and Fe(CO)(eta(5)-C5H5)L. Reaction of Ph2P(CH2)(3)NHPPr2i with PtCl2(PhCN)(2), PtMe2(cod) and PdCl2(PhCN)(2) yields the chelate complexes and reaction with PtClMe(cod) led to a 50:50 mixture of chelate isomers. (C) 2002 Elsevier Science Ltd. All rights reserved.