Phenol, 2,2'-thiobis[6-(1,1-dimethylethyl)-3-methyl- | 13314-01-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Phenol, 2,2'-thiobis[6-(1,1-dimethylethyl)-3-methyl-
• 英文别名: 6-tert-butyl-2-(3-tert-butyl-2-hydroxy-6-methylphenyl)sulfanyl-3-methylphenol
• CAS: 13314-01-7
• 化学式: C₂₂H₃₀O₂S
• 分子量: 358.5
• InChiKey: HJCNGGKJQATACT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  65.8
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• Heteroaryl substituted hydroxyphenyltriazine uv-absorbers
  申请人：——

  公开号：US20040013619A1

  公开（公告）日：2004-01-22

  The present invention provides compounds having the formula (1) in which each of the radicals R 1 , R 2 , R 3 and R 4 , independently, represent hydrogen, hydroxy, halogen, C 1 -C 20 -alkyl, C 1 -C 20 -alkoxy, CN or COOR 5 , in which R 5 is C 1 -C 20 -alkyl and Z represents a heterocyclic residue selected from the 2H-benzo[1,2-d]triazol-2-yl, 2H-naphtho[1,2-d]triazol-2-yl, benzimidazol-2-yl, benzoxazol-2-yl and benzofuran-2-yl moieties, optionally substituted by C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halogen or NHCOC 1 -C 4 -alkyl, a process for their preparation, new intermediate benzoxazinones useful for their preparation and use of the compounds of formula (1) as UV-absorbers which have improved absorption spectrum characteristics, superior resistance to exposure to UV light and excellent thermal stability, relative to known triphenyltriazine compounds.

  本发明提供了具有以下式（1）的化合物，其中R1、R2、R3和R4中的每个基团独立地代表氢、羟基、卤素、C1-C20-烷基、C1-C20-烷氧基、CN或COOR5，其中R5是C1-C20-烷基，Z代表从2H-苯并［1,2-d］三唑-2-基、2H-萘［1,2-d］三唑-2-基、苯并咪唑-2-基、苯并噁唑-2-基和苯并呋喃-2-基残基中选取的杂环残基，可选择地经C1-C4-烷基、C1-C4-烷氧基、卤素或NHCOC1-C4-烷基取代，以及其制备方法，用于其制备的新中间体苯并噁唑酮，以及将式（1）化合物用作具有改善吸收光谱特性、优越的抗紫外光暴露能力和优异的热稳定性的UV吸收剂的用途，相对于已知的三苯基三嗪化合物。
• [EN] A PROCESS FOR THE SYNTHESIS OF AMINE ETHERS<br/>[FR] SYNTHESE D'ETHERS AMINES
  申请人：CIBA SC HOLDING AG

  公开号：WO2005090307A1

  公开（公告）日：2005-09-29

  A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C5-C18alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

  一种制备立体位阻胺醚的方法，包括在有机过氧化物存在的情况下，将相应的立体位阻胺氧化物与C5-C18烯烃反应，可选地对所得产品及其混合物进行氢化处理，并将其用作稳定剂和阻燃剂。
• [EN] ALKYLATED PANA AND DPA COMPOSITIONS<br/>[FR] COMPOSITIONS PANA ET DPA ALKYLEES
  申请人：CIBA SC HOLDING AG

  公开号：WO2005097728A1

  公开（公告）日：2005-10-20

  The invention relates to a composition comprising a mixture of alkylated N-α-naphthyl-N­phenylamine (PANA) and alkylated diphenylamine (DPA), the product obtainable by alkylat­ing PANA or a mixture of PANA and DPA with alkenes and the process for alkylating PANA or a mixture of PANA and DPA with alkenes. The compositions according to the present in­vention have an outstanding anti-oxidative action, which can be demonstrated by established test methods.

  该发明涉及一种组合物，包括烷基化的N-α-萘基-N-苯胺（PANA）和烷基化的二苯胺（DPA）的混合物，所述产品可通过用烯烃烷基化PANA或PANA和DPA的混合物获得，并且涉及用烯烃烷基化PANA或PANA和DPA的混合物的方法。根据本发明的组合物具有出色的抗氧化作用，可通过已建立的测试方法加以证明。
• Stabilized ethylene/chlorotrifluoroethylene copolymer composition
  申请人：Ausimont, U.S.A., Inc.

  公开号：EP0069195A2

  公开（公告）日：1983-01-12

  About equimolar ethylene/chlorotrifluoroethylene copolymer compositions are stabilized against thermal degradation by incorporating therein a stabilizing system comprising (a) a phosphate of an organic polyhydric phenol; (b) a salt of a carboxylic acid and a metal of Group II of the Periodic Table; and (c) an ester of a (4-hydroxy-5-alkylphenyl)alkanoic acid.

  通过在约等摩尔乙烯/三氟氯乙烯共聚物组合物中加入稳定体系来防止热降解，该稳定体系包括：(a) 有机多氢酚的磷酸酯；(b) 羧酸和元素周期表第二族金属的盐；(c) (4-羟基-5-烷基苯基)烷酸的酯。
• Process for producing a modified propylene polymer
  申请人：Chisso Corporation

  公开号：EP0242785A2

  公开（公告）日：1987-10-28

  A modified propylene polymer having exceedingly superior coloring-preventive property is provided according to a process which comprises blending a specified phenolic antioxidant, a polyol or a fatty acid partial ester of the polyol, and a radical generating agent with a propylene polymer containing 5 ppm or more of titanium portion or 0.5 ppm or more of vanadium portion of catalyst residue and subjecting the resultant blend to the melting and kneading treatment at a temperature of 150°C - 300°C.

  一种具有超强防着色性能的改性丙烯聚合物是根据以下工艺制作的：将特定的酚类抗氧化剂、多元醇或多元醇的脂肪酸部分酯和自由基产生剂与含有 5ppm 或更多钛部分或 0.5ppm 或更多钒部分催化剂残留物的丙烯聚合物混合，并将所得混合物在 150°C - 300°C 的温度下进行熔融和捏合处理。