2,4-bis-(Trichloromethyl)-6-(2,4-dimethoxy)styryl-s-triazine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-bis-(Trichloromethyl)-6-(2,4-dimethoxy)styryl-s-triazine
• 英文别名: 2-[(E)-2-(2,4-dimethoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)-1,3,5-triazine
• 化学式: C₁₅H₁₁Cl₆N₃O₂
• 分子量: 478.0
• InChiKey: ANZONXRNCWFEIL-GQCTYLIASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• Oxime derivatives and the use thereof as photoinitiators
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1635220A2

  公开（公告）日：2006-03-15

  Radically photopolymerizable compositions comprising (a) at least one ethylenically unsaturated photopolymerizable compound; (b) as photoinitiator, at least one compound of the formula I, II, III and/or IV wherein m is 0 or 1; n is 0, 1, 2 or 3; x is 1 or 2; R1 is inter alia phenyl, naphthyl, anthracyl or phenanthryl, a heteroaryl radical, C2-C12alkenyl, C4-C8cycloalkenyl, or C6-C12bicycloalkenyl; R'1 is inter alia C2-C12alkylene, or phenylene; R2 has one of the meanings of R1 or inter alia is phenyl; y is 1 or 2; R3 if x is 1 inter alia is C1-C18alkylsulfonyl, or phenyl-C1-C3alkylsulfonyl, R3 if x is 2, is for example C2-C12alkylenedisulfonyl; R4 and R5 inter alia are hydrogen, halogen, or C1-C8alkyl; A is for example -S-, -O-, or -NR10-; R10 inter alia is hydrogen, or phenyl; and (c) at least one coinitiator; are especially suitable for the preparation of colour filter systems.

  具有根据公式I、II、III和/或IV的至少一种化合物作为光引发剂的(radically photopolymerizable compositions)，其中m为0或1；n为0、1、2或3；x为1或2；R1包括苯基、萘基、蒽基或菲基、杂环基、C2-C12烯基、C4-C8环烯基或C6-C12双环烯基；R'1包括C2-C12烷基、苯基或C2-C12烷基苯基；R2具有R1的含义之一或包括苯基；y为1或2；R3如果x为1，则包括C1-C18烷基磺酰基或苯基-C1-C3烷基磺酰基，如果x为2，则例如为C2-C12烷基二磺酰基；R4和R5包括氢、卤素或C1-C8烷基；A例如为-S-、-O-或-NR10-；R10包括氢或苯基等；并且至少包括一种协同引发剂，特别适用于制备彩色滤光片系统。
• (METH)ACRYLIC ACID ESTER, ACTIVATION ENERGY RAY CURING COMPOSITION, AND INKJET RECORDING INK
  申请人：MORITA Mitsunobu

  公开号：US20130144057A1

  公开（公告）日：2013-06-06

  (Meth)acrylic acid ester, which contains one or more partial structures each represented by the following formula 1 in a molecule thereof, wherein the partial structure is a urethane structure which does not have a hydrogen atom directly bonded to a nitrogen atom of the following formula 1: where the nitrogen atom is not bonded to a hydrogen atom.

  (Meth)acrylic acid ester，其中每个分子含有一个或多个由以下式1表示的部分结构，其中该部分结构是一种脲酯结构，不具有直接与以下式1中的氮原子结合的氢原子：其中氮原子未与氢原子结合。
• Chemical amplifying type positive resist composition
  申请人：——

  公开号：US20020168583A1

  公开（公告）日：2002-11-14

  A chemical amplifying type positive resist composition, excellent in balance of performance of resolution and sensitivity, having high dry etching resistance and comprising; a resin having a polymerization unit derived from a monomer represented by the following formula (I): 1 wherein R 1 and R 2 independently represent hydrogen or an alkyl group having 1 to 4 carbons, and R 3 represents hydrogen or a methyl group, the resin being insoluble in alkali itself but becoming alkali-soluble due to the action of an acid; and an acid generating agent is provided.

  一种化学放大型正向光刻胶组合物，其在分辨率和灵敏度性能平衡方面表现出色，具有高干法蚀刻抗性，包括：具有由以下式（I）表示的单体衍生的聚合单元的树脂：1其中R1和R2独立地表示氢或具有1至4个碳的烷基，而R3表示氢或甲基，该树脂本身不溶于碱性物质，但由于酸的作用而变得碱性可溶性；并提供酸发生剂。
• ACTIVE-ENERGY-RAY-CURABLE COMPOSITION, ACTIVE-ENERGY-RAY-CURABLE INK, INK STORED CONTAINER, INK EJECTING DEVICE, METHOD FOR FORMING IMAGE, AND IMAGE
  申请人：MORITA Mitsunobu

  公开号：US20160347960A1

  公开（公告）日：2016-12-01

  To provide an active-energy-ray-curable composition including: a (meth)acrylic acid ester compound represented by General Formula (1) below, where in the General Formula (1), R 1 represents a hydrogen atom or a methyl group, R 2 represents a hydrogen atom, an alkyl group having from 1 through 5 carbon atoms, or an alkyloxy group having from 1 through 5 carbon atoms, n is an integer of from 0 through 5, and X represents an electron-withdrawing functional group.

  提供一种活性光束可固化组合物，包括以下化合物：一种由下式（1）表示的（甲基）丙烯酸酯化合物，在式（1）中，R1表示氢原子或甲基基团，R2表示氢原子、具有1至5个碳原子的烷基基团或具有1至5个碳原子的烷氧基团，n为0至5的整数，X表示电子吸引官能团。
• Oxime ester photoinitiators
  申请人：——

  公开号：US20010012596A1

  公开（公告）日：2001-08-09

  Compounds of the formulae I, II, III, IV and V 1 R 1 i.a. is C 4 -C 9 cycloalkanoyl, C 1 -C 12 alkanoyl, C 4 -C 6 alkenoyl, or benzoyl; R 2 is for example phenyl, C 1 -C 20 alkyl, C 3 -C 8 cycloalkyl, C 2 -C 20 alkanoyl, or benzoyl; Ar 1 is R 4 S-phenyl or NR 5 R 6 -phenyl, each of which optionally is substituted; or Ar, i.a. is 2 optionally substituted; or Ar 1 is naphthyl or anthracyl each of which is unsubstituted or substituted; or Ar 1 is benzoyl, naphthalenecarbonyl, phenanthrenecarbonyl, anthracenecarbonyl or pyrenecarbonyl, each of which is unsubstituted or substituted, or Ar 1 is 3,4,5-trimethoxyphenyl, phenoxyphenyl or biphenyl; Ar 2 i.a. is 3 optionally substituted, or naphthyl or anthracyl, each of which is unsubstituted or substituted, x is 2 or 3; M 1 when x is 2, for example is phenylene, naphthalene, anthracylene, each of which optionally is substituted; M 1 , when x is 3, is a trivalent radical; M 2 for example is 4 M 3 is for example C 1 -C 12 alkylene, cyclohexylene, or phenylene; n is 1-20; R 3 is for example hydrogen or C 1 -C 12 alkyl; R 3 ′ i.a. is C 1 -C 12 alkyl; substituted or -O-interrupted C 2 -C 6 alkyl; R 4 is for example hydrogen, or C 1 -C 12 alkyl; and R 5 and R 6 independently of each other i.a. are hydrogen, C 1 -C 12 alkyl, or phenyl; are suitable as photoinitiators in particular in resist applications.

  式I、II、III、IV和V1R1i.a.的化合物中，C4-C9环烷酰基、C1-C12脂肪酰基、C4-C6烯酰基或苯甲酰基为例；R2例如为苯基、C1-C20烷基、C3-C8环烷基、C2-C20脂肪酰基或苯甲酰基；Ar1为R4S-苯基或NR5R6-苯基，可以选择地取代；或Ar，例如是可选择地取代的；或Ar1为萘基或蒽基，每个都是未取代或取代的；或Ar1为苯甲酰基、萘基甲酰基、菲甲酰基、蒽甲酰基或芘甲酰基，每个都是未取代或取代的，或Ar1为3,4,5-三甲氧基苯基、苯氧基苯基或联苯基；Ar2i.a.是可选择地取代的，或萘基或蒽基，每个都是未取代或取代的，x为2或3；当x为2时，M1例如为苯基、萘基、蒽基，每个可以选择地取代；当x为3时，M1是三价基团；M2例如为4；M3例如为C1-C12亚烷基、环己亚烷基或苯基；n为1-20；R3例如为氢或C1-C12烷基；R3′ i.a.是C1-C12烷基；取代或-O中断的C2-C6烷基；R4例如为氢或C1-C12烷基；R5和R6独立地为氢、C1-C12烷基或苯基；在特别是光刻应用中，适用作光引发剂。