3,4-diphosphinotoluene | 667889-37-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4-diphosphinotoluene
• 英文别名: (4-methyl-o-phenylene)bisphosphine；Phosphine, (4-methyl-1,2-phenylene)bis-；(4-methyl-2-phosphanylphenyl)phosphane
• CAS: 667889-37-4
• 化学式: C₇H₁₀P₂
• 分子量: 156.104
• InChiKey: AWRIJDWKTSVKRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  tetramethyl (4-methyl-o-phenylene)bisphosphonate 在 lithium aluminium tetrahydride 、 三氯化铝 作用下， 以 乙醚 为溶剂， 以50%的产率得到3,4-diphosphinotoluene
  参考文献：
  名称：

  10.1023/a:1024725012685

  摘要：

  DOI：

  10.1023/a:1024725012685

文献信息

• NEMATIC LIQUID CRYSTAL COMPOSITION
  申请人：DIC Corporation

  公开号：EP2835410A1

  公开（公告）日：2015-02-11

  The nematic liquid crystal composition according to the present invention is used for, for example, producing a liquid crystal display elementused in TN mode, OCBmode, ECBmode, IPSmode, or VA-IPS mode. The liquid crystal composition has a positive dielectric anisotropy and allows reductions in refractive-index anisotropy and nematic phase-isotropic liquid phase transition temperature and an increase in the lower limit temperature of a nematic phase to be suppressed. As a result, the liquid crystal composition has a sufficiently low viscosity without deteriorating the temperature range of a nematic phase. The liquid crystal composition allows high-speed response and high display quality to be realized, suppresses faulty display, and is suitably used as a practical liquid crystal composition.

  本发明的向列液晶组合物可用于生产 TN 模式、OCB 模式、ECB 模式、IPS 模式或 VA-IPS 模式的液晶显示元件。液晶组合物具有正的介电各向异性，可抑制折射率各向异性和向列相-各向异性液相转变温度的降低以及向列相下限温度的升高。因此，液晶组合物具有足够低的粘度，同时不会恶化向列相的温度范围。该液晶组合物可实现高速响应和高显示质量，抑制故障显示，适合用作实用液晶组合物。
• 10.1023/a:1024725012685
  作者：Tverdomed、Dogadina、Ionin

  DOI：10.1023/a:1024725012685

  日期：——
• [DE] NEUES VERFAHREN ZUR HERSTELLUNG VON ORGANISCHEN PHOSPHORVERBINDUNGEN, MIT DIESEM VERFAHREN HERGESTELLTE PHOSPHORVERBINDUNGEN, DEREN METALLKOMPLEXE UND VERWENDUNG<br/>[EN] NOVEL METHOD FOR PRODUCING ORGANIC PHOSPHORUS COMPOUNDS, PHOSPHORUS COMPOUNDS PRODUCED USING SAID METHOD, THE METAL COMPLEXES OF SAID COMPOUNDS, AND USE OF SAME<br/>[FR] NOUVEAU PROCÉDÉ DE PRODUCTION DE COMPOSÉS PHOSPHORÉS ORGANIQUES, COMPOSÉS PHOSPHORÉS AINSI OBTENUS, LEURS COMPLEXES MÉTALLIQUES ET LEUR UTILISATION
  申请人：RWTH AACHEN

  公开号：WO2008055963A1

  公开（公告）日：2008-05-15

  [EN] The invention relates to a method for producing organic phosphorus compounds, to organic phosphorus compounds produced using said method, to novel ligand systems containing trivalent and pentavalent phosphorus, to the metal complexes of said compounds, and to the use of the organic phosphorus compounds or ligand systems and metal complexes.
  [FR] L'invention concerne un procédé de production de composés phophorés organiques, comprenant des composés phosphorés organiques obtenus selon ce procédé, nouveaux systèmes ligands avec un phosphore trivalent et pentavalent, leurs complexes métalliques ainsi que l'utilisation des composés phosphorés organiques ou systèmes ligands et complexes métalliques.
  [DE] Die Erfindung betrifft ein Verfahren zur Herstellung von organischen Phophorverbindungen, mit diesem Verfahren hergestellte organische Phosphorverbindungen, neuen Ligandensystem mit dreiwertigem und fünfwertigem Phosphor, deren Metallkomplexe sowie die Verwendung der organischen Phosphorverbindungen bzw. Ligandensysteme und Metallkomplexe.
• A methodology for synthesis of primary o-phenylenebisphosphines and o-chlorophenylphosphines
  作者：S. N. Tverdomed、A. V. Dogadina、B. I. Ionin

  DOI：10.1134/s1070363206060089

  日期：2006.6

  On the basis of the reaction of ethynediylbisphosphonates and chloroethynylphosphonates with classical donor alka-1,3-dienes, a general strategy for synthesis of o-bisphosphanylbenzenes and o-chlorophosphanylbenzenes, which includes two consecutive steps: Diels-Alder condensation -> aromatization of the carbocyclic phosphonate (bisphosphonate) formed -> reduction of the phosphonate groups, was developed. Convenient procedures are devised for aromatization of phosphorus-containing cyclohexa-1,4-dienes and for reduction of o-phenylenebisphosphonates and o-clorophenylphosphonates to primary phosphines. A series of new alkylsubstituted phosphonic chlorides were prepared, and a possibility of functionalization of methyl-substituted o-phenylenebisphosphonates and o-clorophenylphosphonates by the methyl groups is demonstrated.