(6E)-6-[[4-(trifluoromethyl)anilino]methylidene]cyclohexa-2,4-dien-1-one | 25165-80-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (6E)-6-[[4-(trifluoromethyl)anilino]methylidene]cyclohexa-2,4-dien-1-one
• CAS: 25165-80-4
• 化学式: C₁₄H₁₀F₃NO
• 分子量: 265.235
• InChiKey: GTJJEUWREOQQJC-GIJQJNRQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.16
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  32.59
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  CoMe3(PMe3)3 、 (6E)-6-[[4-(trifluoromethyl)anilino]methylidene]cyclohexa-2,4-dien-1-one 以 甲苯 为溶剂， 以16 %的产率得到
  参考文献：
  名称：

  C(sp³)–C(sp³) Reductive Elimination from (Phenoxyimine)Cobalt(III)(CH₃)₂(PMe₃)₂ Complexes

  摘要：

  A series of six-coordinate, idealized octahedral phenoxyimine (FI)–cobalt(III) dimethyl bis(trimethylphosphine) complexes was synthesized and characterized by NMR spectroscopy and single-crystal X-ray diffraction. The thermal stability of the parent Ph-FI complex was evaluated at 60 °C in benzene-d6, and a 13(1):1 ratio of ethane to methane was observed. The major detectable cobalt product of this

  DOI：

  10.1021/acs.organomet.4c00070

文献信息

• SCHIFF BASE TYPE COMPOUND AND COLORING MATERIAL CONTAINING THE SAME
  申请人：Okada Mitsuhiro

  公开号：US20110135958A1

  公开（公告）日：2011-06-09

  Disclosed are a compound that emits fluorescence, particularly in its solid state, and is suited to provide a color converting material with various improved performance properties over prior art and a light emitter, a color conversion filter, a color conversion device, and a photoelectric device each containing the compound; particularly a Schiff base type compound of formula (I) and a coloring material, a color conversion layer, a light absorbing layer, a color conversion filter, a light absorbing filter, a color-converting light-emitting device, and a photoelectric device each containing the compound. The definition of the symbols in formula (I) is the same as in the specification.

  本发明涉及一种化合物，特别是在其固态下发出荧光，并适用于提供具有各种改进性能特性的颜色转换材料，以及包含该化合物的光发射器、颜色转换滤光片、颜色转换装置和光电器件；特别是一种式（I）的席夫碱型化合物和一种着色材料、颜色转换层、吸光层、颜色转换滤光片、吸光滤光片、颜色转换发光器件和光电器件，每个都包含该化合物。式（I）中符号的定义与规范中的相同。
• SCHIFF BASE TYPE COLOR CONVERSION LAYER, LIGHT ABSORBING LAYER, AND FILTER
  申请人：ADEKA CORPORATION

  公开号：US20130252024A1

  公开（公告）日：2013-09-26

  Disclosed are a compound that emits fluorescence, particularly in its solid state, and is suited to provide a color converting material with various improved performance properties over prior art and a light emitter, a color conversion filter, a color conversion device, and a photoelectric device each containing the compound; particularly a Schiff base type compound of formula (I) and a coloring material, a color conversion layer, a light absorbing layer, a color conversion filter, a light absorbing filter, a color-converting light-emitting device, and a photoelectric device each containing the compound. The definition of the symbols in formula (I) is the same as in the specification.
• US4176198A
  申请人：——

  公开号：US4176198A

  公开（公告）日：1979-11-27
• US8568884B2
  申请人：——

  公开号：US8568884B2

  公开（公告）日：2013-10-29
• US8758897B2
  申请人：——

  公开号：US8758897B2

  公开（公告）日：2014-06-24