4-[[2,3,5,6-Tetrafluoro-4-[3-[3-[3-[2,3,5,6-tetrafluoro-4-(pyridin-4-ylmethyl)phenyl]phenyl]phenyl]phenyl]phenyl]methyl]pyridine | 477284-92-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[[2,3,5,6-Tetrafluoro-4-[3-[3-[3-[2,3,5,6-tetrafluoro-4-(pyridin-4-ylmethyl)phenyl]phenyl]phenyl]phenyl]phenyl]methyl]pyridine
• CAS: 477284-92-7
• 化学式: C₄₂H₂₄F₈N₂
• 分子量: 708.653
• InChiKey: NOABIUBESGGTFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  52
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  4-[[2,3,5,6-Tetrafluoro-4-[3-[3-[3-[2,3,5,6-tetrafluoro-4-(pyridin-4-ylmethyl)phenyl]phenyl]phenyl]phenyl]phenyl]methyl]pyridine 、 Pt(ethylenediamine)(NO₃)₂ 以 not given 为溶剂， 生成 [Pt(en)(C6H4(C6H4C6F4CH2C5H4N)2)](2+)
  参考文献：
  名称：

  Photoswitchable Molecular Lock. One-Way Catenation of a Pt(II)-Linked Coordination Ring via the Photolabilization of a Pt(II)−Pyridine Bond

  摘要：

  An inert Pt(II)-py bond (py = pyridyl) is considerably labilized upon UV irradiation. On the basis of this phenomenon, a kinetically inert Pt(II)-linked coordination ring is rapidly catenated on irradiation via Pt(II)-py photodissociation.

  DOI：

  10.1021/ja067132y

文献信息

• A circular tris[2]catenane from molecular ‘figure-of-eight’
  作者：Akiko Hori、Ken-ichi Yamashita、Takahiro Kusukawa、Akihiko Akasaka、Kumar Biradha、Makoto Fujita

  DOI：10.1039/b407108e

  日期：——

  A 'figure-of-eight'-shaped molecule with Pd(ii) at the node was self-assembled into an unprecedented circular tris[2]catenane via reversible double catenation at both loops of the 'figure-of-eight' molecule.

  一个在节点上带有Pd（ii）的“八位数”形状的分子通过在“八位数”分子的两个环处可逆的双重连接而自组装成前所未有的圆形tris [2] catenane。
• Chirality Induction through the Reversible Catenation of Coordination Rings
  作者：Akiko Hori、Akihiko Akasaka、Kumar Biradha、Shigeru Sakamoto、Kentaro Yamaguchi、Makoto Fujita

  DOI：10.1002/1521-3773(20020902)41:17<3269::aid-anie3269>3.0.co;2-9

  日期：2002.9.2
• Ultramacrocyclization through Reversible Catenation
  作者：Akiko Hori、Tomohisa Sawada、Ken-ichi Yamashita、Makoto Fujita

  DOI：10.1002/anie.200501559

  日期：2005.8.5
• Photoswitchable Molecular Lock. One-Way Catenation of a Pt(II)-Linked Coordination Ring via the Photolabilization of a Pt(II)−Pyridine Bond
  作者：Ken-ichi Yamashita、Masaki Kawano、Makoto Fujita

  DOI：10.1021/ja067132y

  日期：2007.2.1

  An inert Pt(II)-py bond (py = pyridyl) is considerably labilized upon UV irradiation. On the basis of this phenomenon, a kinetically inert Pt(II)-linked coordination ring is rapidly catenated on irradiation via Pt(II)-py photodissociation.