2,2':6',2''-Terpyridine, 4,4',4''-tris(1-butylpentyl)- | 258262-76-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,2':6',2''-Terpyridine, 4,4',4''-tris(1-butylpentyl)-
• 英文别名: 4-nonan-5-yl-2,6-bis(4-nonan-5-ylpyridin-2-yl)pyridine
• CAS: 258262-76-9
• 化学式: C₄₂H₆₅N₃
• 分子量: 612.0
• InChiKey: GLZSMQYMDHZSPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.2
• 重原子数：
  45
• 可旋转键数：
  23
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] AMINO-REACTIVE POSITIVELY CHARGED ATRP INITIATORS THAT MAINTAIN THEIR POSITIVE CHARGE DURING SYNTHESIS OF BIOMACRO-INITIATORS<br/>[FR] INITIATEURS ATRP À CHARGE POSITIVE AMINO-RÉACTIFS MAINTENANT LEUR CHARGE POSITIVE PENDANT LA SYNTHÈSE DE BIOMACRO-INITIATEURS
  申请人：RUSSELL ALAN J

  公开号：WO2020028715A1

  公开（公告）日：2020-02-06

  Provided herein are materials and methods that include utilizing atom transfer radical polymerization (ATRP) initiator molecules that maintain a positive charge during biomacro-initiator synthesis.

  本文提供的材料和方法包括利用原子转移自由基聚合（ATRP）引发剂分子，在生物大分子引发剂合成过程中保持正电荷。
• DENDRITIC MOLECULES
  申请人：Monteiro Michael John

  公开号：US20120059173A1

  公开（公告）日：2012-03-08

  The invention relates to novel dendritic molecules and methods of making them. The dendritic molecules comprise arms, each of which arms is a polymer. The dendritic molecules can be synthesised by way of a reasonably small number of versatile and reliable step-wise reactions, especially click chemistry reactions. Chemical and structural heterogeneity is possible in the dendritic molecule. The invention also provides for surface and interior functionalisation of the molecule.

  该发明涉及新型树状分子及其制备方法。这些树状分子包括臂，每个臂都是一种聚合物。这些树状分子可以通过相对少量的多功能和可靠的逐步反应合成，特别是点击化学反应。树状分子中可能存在化学和结构上的异质性。该发明还提供了对分子的表面和内部功能化。
• IMPROVED CONTROLLED RADICAL POLYMERIZATION PROCESSES
  申请人：Matyjaszewski Krzysztof

  公开号：US20110046324A1

  公开（公告）日：2011-02-24

  A transition metal mediated chain transfer agent controlled polymerization process is described. The process combines the advantages of atom transfer radical polymerization (ATRP) and reversible addition fragmentation transfer (RAFT) polymerization. Synthesis of chain transfer agents useful in the disclosed processes is also disclosed. Other improvements on ATRP RAFT processes are also described.

  本文描述了一种过渡金属介导的链转移剂控制聚合过程。该过程结合了原子转移自由基聚合（ATRP）和可逆加成裂解转移（RAFT）聚合的优点。还公开了在所述过程中有用的链转移剂的合成方法。还描述了ATRP RAFT过程的其他改进。
• PROTEIN-POLYMER CONJUGATES AND METHODS FOR THEIR PREPARATION
  申请人：Carnegie Mellon University

  公开号：US20210388337A1

  公开（公告）日：2021-12-16

  This document relates to materials and methods for using controlled radical polymerization (e.g., atom transfer radical polymerization) to generate protein-polymer conjugates in which two or more polymer molecules are attached to individual initiator molecules on the protein.

  本文件涉及使用受控自由基聚合（例如原子转移自由基聚合）的材料和方法，以生成蛋白质-聚合物共轭物，在其中两个或更多的聚合物分子附着在蛋白质上的单个引发剂分子上。
• Catalytic processes for the controlled polymerization of free radically (Co)polymerizable monomers and functional polymeric systems prepared thereby
  申请人：Carnegie Mellon University (a non-profit Pennsylvania organization)

  公开号：US20040171779A1

  公开（公告）日：2004-09-02

  Further improvements have been made in processes for controlled polymerization of free radically (co)polymerizable monomers mediated by a transition metal complex participating in a redox reaction which involves transfer of a radically transferable atom or group to and from an initiator or dormant polymer and the growing active polymer chain ends. Two improvements involve the choice of counterion in the transition metal complex. In one improvement the transition metal is held in close conjunction with a solid support through interaction with a counterion directly attached to the support. This cognition also allows for improvements in catalyst utilization including catalyst recovery and recycle. In another improvement, particularly suitable for controlled polymerization of certain monomers with an expanded range of transition metals, the function of counterion and ligand in the development of the transition metal based catalyst is superseded by use of salt containing a soluble organic counterion. These and other process improvements have been employed to prepare an extended range of novel polymeric materials and novel processes for the preparation of functional polymers including a novel catalytic Atom Transfer Coupling Reaction.

  在控制自由基（共）聚合单体的过程中，通过参与氧化还原反应的过渡金属配合物介导，将可自由基转移的原子或基团从引发剂或休眠聚合物传递到活性聚合物链末端，进一步改进了工艺。其中两项改进涉及过渡金属配合物中对离子的选择。在一种改进中，通过与直接附着于支撑物的对离子相互作用，将过渡金属紧密结合于固体支撑物上。这种认知还可以改善催化剂的利用率，包括催化剂的回收和循环利用。在另一项改进中，特别适用于具有扩展过渡金属范围的某些单体的控制聚合，对离子和配体在过渡金属基催化剂的发展中的作用被含有可溶性有机对离子的盐所取代。这些和其他工艺改进已被用于制备一系列新型聚合材料和制备功能性聚合物的新型工艺，包括一种新型的催化原子转移偶联反应。