(2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4,4''-tetraisopropyl-m-terphenyl-2'-yl)Sn: | 905703-20-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4,4''-tetraisopropyl-m-terphenyl-2'-yl)Sn:
• 英文别名: (2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4.4''-tetraisopripyl-m-terphenyl-2'-yl)Sn
• CAS: 905703-20-0
• 化学式: C₆₀H₁₀₄Si₇Sn
• 分子量: 1140.79
• InChiKey: ULGBKVGADCRMJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.52
• 重原子数：
  68
• 可旋转键数：
  16
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4,4''-tetraisopropyl-m-terphenyl-2'-yl)Sn: 以 正己烷 为溶剂， 生成 (2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4.4''-tetraisopripyl-m-terphenyl-2'-yl)Sn(OH)2
  参考文献：
  名称：

  A Kinetically Stabilized Stannanetellone, a Tin−Tellurium Double-Bonded Compound

  摘要：

  A kinetically stabilized stannanetellone was synthesized by the telluration of an extremely hindered stannylene with (n-Bu)(3)Pd=Te. The structure of the stannanetellone was determined by X-ray crystallographic analysis.

  DOI：

  10.1021/om0604627
• 作为产物：
  描述：

  (2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4,4''-tetraisopropyl-m-terphenyl-2'-yl)SnBr2 在 KC₈ 作用下， 以 苯 为溶剂， 以52%的产率得到(2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl)(2,2'',4,4''-tetraisopropyl-m-terphenyl-2'-yl)Sn:
  参考文献：
  名称：

  A Kinetically Stabilized Stannanetellone, a Tin−Tellurium Double-Bonded Compound

  摘要：

  A kinetically stabilized stannanetellone was synthesized by the telluration of an extremely hindered stannylene with (n-Bu)(3)Pd=Te. The structure of the stannanetellone was determined by X-ray crystallographic analysis.

  DOI：

  10.1021/om0604627

文献信息

• A Kinetically Stabilized Stannanetellone, a Tin−Tellurium Double-Bonded Compound
  作者：Tomoyuki Tajima、Nobuhiro Takeda、Takahiro Sasamori、Norihiro Tokitoh

  DOI：10.1021/om0604627

  日期：2006.7.1

  A kinetically stabilized stannanetellone was synthesized by the telluration of an extremely hindered stannylene with (n-Bu)(3)Pd=Te. The structure of the stannanetellone was determined by X-ray crystallographic analysis.