3-(heptadecafluoro-n-octylphenyl)diphenylphosphine | 941293-73-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(heptadecafluoro-n-octylphenyl)diphenylphosphine
• 英文别名: [3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluorooctyl)phenyl]-diphenylphosphane；[3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]-diphenylphosphane
• CAS: 941293-73-8
• 化学式: C₂₆H₁₄F₁₇P
• 分子量: 680.344
• InChiKey: POMOHMAVMZXWFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  44
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  bis(acetonitrile)dichloroplatinum(II) 、 3-(heptadecafluoro-n-octylphenyl)diphenylphosphine 以 二氯甲烷 为溶剂， 生成 PtCl2(3-(heptadecafluoro-n-octylphenyl)diphenylphosphine)2
  参考文献：
  名称：

  Synthesis and characterisation of trisarylphosphine selenides: Further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines

  摘要：

  Variations in the magnitude of the lis, coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.025

文献信息

• Synthesis and characterisation of trisarylphosphine selenides: Further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines
  作者：Dave J. Adams、James A. Bennett、Daniel Duncan、Eric G. Hope、Jonathan Hopewell、Alison M. Stuart、Andrew J. West

  DOI：10.1016/j.poly.2006.11.025

  日期：2007.5

  Variations in the magnitude of the lis, coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established. (C) 2006 Elsevier Ltd. All rights reserved.