1-Ethyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium | 157014-73-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-Ethyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium
• CAS: 157014-73-8
• 化学式: C₁₃H₁₆N₂
• 分子量: 200.283
• InChiKey: PNFINSJZIBDSNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  7.8
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-Ethyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium 在 三丁基膦 作用下， 以 甲醇 、 乙腈 为溶剂， 生成 N-ethyl-N'-methyl-4,4'-bipyridylium
  参考文献：
  名称：

  从三丁基膦到紫精的单电子转移中的动力学氘同位素效应

  摘要：

  单电子转移 (SET) 在乙腈-甲醇中从三丁基膦 (1) 到 1-甲基-1'-烷基-4,4'-联吡啶盐（紫精；2）发生。对于 2 中的甲基（或乙基）取代基的氢，已观察到显着的动力学氘同位素效应。 根据发生在 1 和 2 之间形成的紧密接触复合物中的 SET 来解释结果。

  DOI：

  10.1246/cl.2001.1056
• 作为产物：
  描述：

  N-ethyl-4,4'-bipyridine 、 碘甲烷 生成 1-Ethyl-4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium
  参考文献：
  名称：

  不对称n，n'-二芳基-;的超精细偶合常数的赋值 n，n′-二烷基-；和n-烷基-n'-芳基-4,4'-联吡啶鎓自由基阳离子

  摘要：

  对于其中烷基和芳基季铵化基团以混合方式出现的不对称双季铵4,4'-联吡啶鎓化合物的自由基阳离子，获得了ESR和多重共振谱。这些基团对联吡啶质子的影响已显示出明显的趋势，这些趋势可用于预测不容易氘化的位置的分配。

  DOI：

  10.1016/s0040-4020(01)87710-3

文献信息

• PROCESS FOR PRODUCTION OF SULFONIC ACID ESTER
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：EP2067770B1

  公开（公告）日：2017-04-12
• Microwave-assisted synthesis of symmetric and asymmetric viologens
  作者：Massimiliano Lamberto、Elizabeth E. Rastede、Justyne Decker、Françisco M. Raymo

  DOI：10.1016/j.tetlet.2010.08.070

  日期：2010.10

  Viologens are generally synthesized by N-alkylating 4,4'-bipyridine with alkyl halides. Under conventional heating conditions, however, their synthesis suffers from long reaction times and, often, low yields. In this work, symmetric and asymmetric viologens were synthesized under the assistance of microwave irradiation in good to excellent yields and in short reaction times. (c) 2010 Elsevier Ltd. All rights reserved.
• VEHICULAR EXTERIOR MIRROR
  申请人：Varaprasad V. Desaraju

  公开号：US20080094685A1

  公开（公告）日：2008-04-24

  An exterior mirror suitable for use in a vehicular exterior rearview mirror assembly includes a reflective mirror element having a light transmitting substrate with a mirror reflector having a metallic reflective layer coated thereon. A visual indicator display is disposed to the rear of the light transmitting substrate and actuated to emit light when powered. Light emitted by light sources of the display passes through the light transmitting substrate so as to be viewed by a driver of the vehicle equipped with the reflective mirror element. The mirror element has portions of the metallic reflective layer at least partially removed by laser scribing to establish at least partially light transmissive portions of the mirror reflector so that light emitted by light sources, when powered, passes through the respective at least partially light transmissive portions to be viewed by a viewer viewing from the front of the reflective mirror element.
• LIQUID ELECTROLYTE-FREE, SOLID-STATE SOLAR CELLS WITH INORGANIC HOLE TRANSPORT MATERIALS
  申请人：NORTHWESTERN UNIVERSITY

  公开号：US20130233377A1

  公开（公告）日：2013-09-12

  Photovoltaic cells incorporating the compounds A/M/X compounds as hole transport materials are provide. The A/M/X compounds comprise one or more A moieties, one or more M atoms and one or more X atoms. The A moieties are selected from organic cations and elements from Group 1 of the periodic table, the M atoms are selected from elements from at least one of Groups 3, 4, 5, 13, 14 or 15 of the periodic table, and the X atoms are selected from elements from Group 17 of the periodic table.
• PHOTOLUMINESCENT COMPOUNDS
  申请人：Northwestern University

  公开号：US20160102248A1

  公开（公告）日：2016-04-14

  Materials comprising an A/M/X compound are provided. An A/M/X compound is a compound comprising one or more A moieties, one or more M atoms and one or more X atoms, where the A moieties are selected from organic cations and elements from Group 1 of the periodic table, the M atoms are selected from elements from Group 14 of the periodic table, and the X atoms are selected from elements from Group 17 of the periodic table. The materials include two-phase materials.