tri(m-tolyl)amine | 20676-79-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tri(m-tolyl)amine
• 英文别名: Benzenamine, 3-methyl-N,N-bis(3-methylphenyl)-；3-methyl-N,N-bis(3-methylphenyl)aniline
• CAS: 20676-79-3
• 化学式: C₂₁H₂₁N
• 分子量: 287.404
• InChiKey: PMOOWLLUDONVHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N,N-tris(3-methylphenyl)amine 、 tri(m-tolyl)amine 以 1,2-二氯乙烷 为溶剂， 生成 Tri-m-tolyl-amine; compound with tri-m-tolyl-amine
  参考文献：
  名称：

  三苯胺二聚体阳离子形成速率常数及取代基效应

  摘要：

  三苯胺和甲基取代的三苯胺在 1,2-二氯乙烷中的脉冲辐解研究表明，二聚体阳离子的形成是主要的过程，在寄生位点的耦合占主导地位。获得了瞬态二聚体阳离子的光谱，在 400 和 850 nm 处具有 λmax，二聚化速率常数 k = 1.3 × 108 dm3 mol-1 s-1。

  DOI：

  10.1246/cl.1995.645

文献信息

• SILYL COMPOUND, LIGHT EMITTING MATERIAL, AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：Saitoh Akihito

  公开号：US20070205715A1

  公开（公告）日：2007-09-06

  Provided is an organic light emitting device capable of emitting light with high efficiency by incorporating a silyl compound in which a silyl group is directly bonded to an anthracene ring particularly into its light emitting layer. In the organic light emitting device including: a pair of electrodes formed of an anode and a cathode, at least one of which being transparent or semi-transparent; and one or more layers containing an organic compound layer interposed between the pair of electrodes, at least one of the layer containing the organic compound contains the following silyl compound, and a layer containing at least one kind of the silyl compound is a light emitting layer.

  提供的是一种有机发光器件，通过将一个硅基团直接连接到蒽环中的硅基化合物纳入其发光层中，能够高效地发出光。该有机发光器件包括：一对电极，由阳极和阴极组成，其中至少一个是透明或半透明的；以及夹在电极对之间的一个或多个含有有机化合物层的层，其中至少一个含有以下硅基化合物，同时至少一个含有硅基化合物的层是发光层。
• Organic electroluminescence material and electroluminescence device using the same
  申请人：——

  公开号：US20040018387A1

  公开（公告）日：2004-01-29

  An organic electroluminescence material of the present invention includes, in order to provide a durable organic EL device emitting light of high brightness, a compound shown by the following general formula (A-I) or (B-I) 1 (B-I) wherein, A 1 to A 3 , which may be the same or different, are independently each a substituent shown by the general formula (A-II): 2 and a 1 , b 1 and b 2 are independently each an aryl group which may be substituted, a 1 having at least one substituent shown by the general formula (B-II), and b 1 and b 2 each having at least one substituent shown by the general formula (B-III), and b 1 and b 2 may be the same or different. 3

  本发明的有机电致发光材料包括以下通式（A-I）或（B-I）1（B-I）所示的化合物，以提供具有高亮度的持久有机电致发光装置，其中A1到A3可以相同也可以不同，分别独立地表示由通式（A-II）所示的取代基：2，a1、b1和b2分别独立地表示可以被取代的芳基，a1至少具有一个由通式（B-II）所示的取代基，而b1和b2各自至少具有一个由通式（B-III）所示的取代基，且b1和b2可以相同也可以不同。3
• ORGANIC ELECTROLUMINESCENCE MATERIAL AND ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Tada Hiroshi

  公开号：US20060263639A1

  公开（公告）日：2006-11-23

  An organic electroluminescence material of the present invention includes, in order to provide an durable organic EL device emitting light of high brightness, a compound shown by the general formula (A-I) or (B-I) (as explained in the specification) wherein, A 1 to A 3 which may be the same or different, are independently each a substituent shown by the general formula (A-II) (as explained in the specification): and a 1 , b 1 , and b 2 are independently each an aryl group which may be substituted, a 1 having at least one substituent shown by the general formula (B-II) (as explained in the specification), and b 1 and b 2 each having at least one substituent shown by the general formula (B-III) (as explained in the specification), and b 1 and b 2 may be the same of different.

  本发明的有机电致发光材料包括化合物，以提供一种持久的有机EL器件，该器件发出高亮度的光，所述化合物由通式（A-I）或（B-I）（在规范中解释）所示的化合物组成，其中A1至A3可以相同或不同，分别独立地是由通式（A-II）（在规范中解释）所示的取代基，而a1，b1和b2则分别是可以被取代的芳基，其中a1至少具有由通式（B-II）（在规范中解释）所示的一个取代基，而b1和b2分别具有由通式（B-III）（在规范中解释）所示的一个或多个取代基，且b1和b2可以相同或不同。
• Benzofuran compounds
  申请人：——

  公开号：US20030105343A1

  公开（公告）日：2003-06-05

  There is disclosed a method of preparing a branched benzofuran compound comprising a core moiety which contains at least one aromatic ring and which has at least three substituted or unsubstituted benzofuran groups covalently linked thereto. The method comprises the steps of (i) forming an intermediate ethynylene compound in which at least three benzene rings are each linked to the core moiety via an ethynylene bond, and where each benzene ring is substituted at the ortho position (relative to the position of the ethynylene bond) by a blocked carbonyloxy group, (ii) deblocking the carbonyloxy groups, and (iii) effecting ring closure by reaction between the deblocked carbonyloxy groups and the adjacent ethynylene bonds to form the furan rings of the benzofuran groups, whereby to produce the branched benzofuran compound.

  公开了一种制备支链苯并呋喃化合物的方法，其包含至少一个芳香环核心基团，且至少有三个取代或未取代的苯并呋喃基团与其共价键合。该方法包括以下步骤：(i)形成中间乙炔基化合物，在该化合物中，至少有三个苯环通过乙炔基键与核心基团连接，且每个苯环在邻位（相对于乙炔基键的位置）处被阻断的羰基氧基团取代，(ii)去除羰基氧基团，以及(iii)通过去除羰基氧基团和相邻乙炔基键之间的反应进行环闭合，形成苯并呋喃基团的呋喃环，从而产生支链苯并呋喃化合物。
• Organic electroluminescent material and electroluminescent device using the same
  申请人：NEC CORPORATION

  公开号：EP1074601A2

  公开（公告）日：2001-02-07

  An organic electroluminescence material of the present invention includes, in order to provide a durable organic EL device emitting light of high brightness, a compound shown by the following general formula (A-I) or (B-I) wherein, A1 to A3, which may be the same or different, are independently each a substituent shown by the general formula (A-II): and a1, b1 and b2 are independently each an aryl group which may be substituted, a1 having at least one substituent shown by the general formula (B-II), and b1 and b2 each having at least one substituent shown by the general formula (B-III), and b1 and b2 may be the same or different.

  本发明的一种有机电致发光材料包括如下通式（A-I）或（B-I）所示的化合物，以提供一种能发出高亮度光的耐用有机电致发光器件 其中，A1 至 A3（可以相同或不同）各自独立地为通式（A-II）所示的取代基： a1、b1 和 b2 各自独立地为可被取代的芳基，a1 具有通式（B-II）所示的至少一个取代基，b1 和 b2 各自具有通式（B-III）所示的至少一个取代基，且 b1 和 b2 可以相同或不同。