1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane | 143200-51-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane
• 英文别名: 1,10,19,28-tetraoxo-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane；1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octazacyclohexatriacontane
• CAS: 143200-51-5
• 化学式: C₂₄H₅₆N₈O₄
• 分子量: 520.76
• InChiKey: AMFHQRFBYIDMKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4
• 重原子数：
  36
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  133
• 氢给体数：
  8
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane 在 sodium hydroxide 作用下， 以 水 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Synthesis of 1,10,19,28-tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane (L) and its complex [Cu₄L(OH)₄][ClO₄]₄·2H₂O

  摘要：

  A 36-membered macrocycle with four ethylenediamine entities, 1,1019,28-tetraoxa-4,7,13,1 6,22,25,31,34-octaazacyclohexatriacontane (L), has been synthesized and characterized by H-1 and C-13 NMR and fast atom bombardment (FAB) mass spectra. Its complexing behaviour toward copper(II) ion was investigated spectroscopically and the macrocycle shown to incorporate four copper(II) ions in the range pH 6-9. A tetranuclear complex [Cu4L(OH)4] [ClO4]4.2H2O was obtained and characterized to be of a cubane-type Cu4(OH)4 core surrounded by the macrocycle, according to IR, visible, FAB and ESR spectra, cyclic voltammetry, and cryomagnetic susceptibility.

  DOI：

  10.1039/dt9920001121
• 作为产物：
  描述：

  1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octa(toluene-p-sulfonyl)-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane 在 氢溴酸 、 苯酚 作用下， 以 溶剂黄146 为溶剂， 反应 14.0h， 生成 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane
  参考文献：
  名称：

  Synthesis of 1,10,19,28-tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane (L) and its complex [Cu₄L(OH)₄][ClO₄]₄·2H₂O

  摘要：

  A 36-membered macrocycle with four ethylenediamine entities, 1,1019,28-tetraoxa-4,7,13,1 6,22,25,31,34-octaazacyclohexatriacontane (L), has been synthesized and characterized by H-1 and C-13 NMR and fast atom bombardment (FAB) mass spectra. Its complexing behaviour toward copper(II) ion was investigated spectroscopically and the macrocycle shown to incorporate four copper(II) ions in the range pH 6-9. A tetranuclear complex [Cu4L(OH)4] [ClO4]4.2H2O was obtained and characterized to be of a cubane-type Cu4(OH)4 core surrounded by the macrocycle, according to IR, visible, FAB and ESR spectra, cyclic voltammetry, and cryomagnetic susceptibility.

  DOI：

  10.1039/dt9920001121

文献信息

• Synthesis of 1,10,19,28-tetraoxa-4,7,13,16,22,25,31,34-octaazacyclohexatriacontane (L) and its complex [Cu₄L(OH)₄][ClO₄]₄·2H₂O
  作者：Teruko Shimada、Masahito Kodera、Hisashi Ōkawa、Sigeo Kida

  DOI：10.1039/dt9920001121

  日期：——

  A 36-membered macrocycle with four ethylenediamine entities, 1,1019,28-tetraoxa-4,7,13,1 6,22,25,31,34-octaazacyclohexatriacontane (L), has been synthesized and characterized by H-1 and C-13 NMR and fast atom bombardment (FAB) mass spectra. Its complexing behaviour toward copper(II) ion was investigated spectroscopically and the macrocycle shown to incorporate four copper(II) ions in the range pH 6-9. A tetranuclear complex [Cu4L(OH)4] [ClO4]4.2H2O was obtained and characterized to be of a cubane-type Cu4(OH)4 core surrounded by the macrocycle, according to IR, visible, FAB and ESR spectra, cyclic voltammetry, and cryomagnetic susceptibility.