tetra-N-phenyl-propanediyldiamine | 99703-78-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tetra-N-phenyl-propanediyldiamine
• 英文别名: Tetra-N-phenyl-propandiyldiamin；N,N,N',N'-tetraphenylpropane-1,3-diamine
• CAS: 99703-78-3
• 化学式: C₂₇H₂₆N₂
• 分子量: 378.517
• InChiKey: XBQOUDNPIDPETH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  29
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetra-N-phenyl-propanediyldiamine 以 乙腈 为溶剂， 生成 (3-Carbazol-9-yl-propyl)-diphenyl-amine
  参考文献：
  名称：

  双功能化合物及其配合物的光谱和光化学性质

  摘要：

  测量了二苯胺 (DPA) 衍生物 Ph2N−(CH2)n−NPh2,n=3–6, 9 逐步光环化到相应的 α,ω-二（咔唑基）烷烃的量子产率。当n>3时，第二个DPA基团的存在对第一个DPA基团的环化没有影响；然而，在第一个 DPA 基团环化后，第二个 DPA 基团的环化被延迟。通过半环状化合物中新形成的咔唑基团猝灭激发的 DPA 基团来解释该效应。对于双取代丙烷（n=3），发现了两个基团在反应的两个阶段的相互影响。

  DOI：

  10.1007/bf02496398
• 作为产物：
  描述：

  1,3-丙二醇-二-间-甲苯磺酸盐 、 二苯胺 生成 tetra-N-phenyl-propanediyldiamine
  参考文献：
  名称：

  Preparation of N,N,N',N'-Tetrasubstituted Diamines

  摘要：

  DOI：

  10.1021/ja01151a521

文献信息

• Catalyst for Olefin Polymerization Process for Producing Olefin Polymer, Olefin Copolymer, Novel Transition Metal Compound, and Process for Producing Transition Metal Compound
  申请人：Michiue Kenji

  公开号：US20070260026A1

  公开（公告）日：2007-11-08

  [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties. [Construction] A catalyst for olefin polymerization comprising (A) a transition metal compound represented by the following general formula (1); and (B) at least one compound selected from the group consisting of (B-1) organometallic compound, (B-2) organoaluminum oxy compound and (B-3) compounds capable of reacting with the transition metal compound (A) to form an ion pair: (M is a transition metal atom selected from Groups 4 to 6 of the periodic table; the two of R 1 to R 4 , which are adjacent to each other, are combined to form a ring with the carbon atoms to which the two are bonded; groups of not forming a ring, R 5 to R 8 , and X are each an atom or a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing group, and a nitrogen-containing group; Q is —O—, —S—, —NR a —, or —PR b — (R a and R b are each a hydrogen atom or a hydrocarbon group); Y is a neutral ligand having an electron-donating group; m is a number satisfying the valence of M; and n is an integer of 0 to 3.).

  [任务] 提供一种具有优异的烯烃聚合性能并能够生产具有优异性能的聚烯烃的催化剂。 [构造] 一种烯烃聚合的催化剂，包括（A）由下列通式（1）表示的过渡金属化合物和（B）选自以下组合中的至少一种化合物（B-1）有机金属化合物，（B-2）有机铝氧化合物和（B-3）能够与过渡金属化合物（A）反应形成离子对的化合物： （M是周期表第4到第6族中选择的过渡金属原子；R1到R4中的两个相邻的基团与它们所连接的碳原子形成一个环；不形成环的基团R5到R8和X是选择自氢原子，卤素原子，烃基，卤代烃基，含氧基团和含氮基团的原子或基团；Q是—O—，—S—，—NRa—或—PRb—（Ra和Rb分别是氢原子或烃基）；Y是带有电子给体基团的中性配体；m是满足M的价的数字；n是0到3之间的整数。）
• Catalyst for olefin polymerization, process for producing olefin polymer, olefin copolymer, novel transition metal compound, and process for producing transition metal compound
  申请人：Michiue Kenji

  公开号：US20100267908A1

  公开（公告）日：2010-10-21

  [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties. [Construction] A catalyst for olefin polymerization comprising (A) a transition metal compound represented by the following general formula (1); and (B) at least one compound selected from the group consisting of (B-1) organometallic compound, (B-2) organoaluminum oxy compound and (B-3) compounds capable of reacting with the transition metal compound (A) to form an ion pair: (M is a transition metal atom selected from Groups 4 to 6 of the periodic table; the two of R 1 to R 4 , which are adjacent to each other, are combined to form a ring with the carbon atoms to which the two are bonded; groups of not forming a ring, R 5 to R 8 , and X are each an atom or a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing group, and a nitrogen-containing group; Q is —O—, —S—, —NR a —, or —PR b — (R a and R b are each a hydrogen atom or a hydrocarbon group); Y is a neutral ligand having an electron-donating group; m is a number satisfying the valence of M; and n is an integer of 0 to 3.).

  [任务] 提供一种催化剂，具有优异的烯烃聚合性能，并能生产出具有优异性能的聚烯烃。[构成] 一种烯烃聚合催化剂，包括（A）由以下通式（1）表示的过渡金属化合物；以及（B）选自以下组中的至少一种化合物（B-1）有机金属化合物，（B-2）有机铝氧化合物和（B-3）能够与过渡金属化合物（A）反应形成离子对的化合物：（M是从周期表的第4到第6组选择的过渡金属原子；R1至R4中相邻的两个与它们结合的碳原子形成环；不形成环的基团R5至R8和X均为氢原子，卤素原子，碳氢基团，卤化碳氢基团，含氧基团和含氮基团中选择的原子或基团；Q为—O—，—S—，—NRa—或—PRb—（Ra和Rb均为氢原子或碳氢基团）；Y是具有电子给体基团的中性配体；m是满足M的价的数字；n是0到3的整数。
• Process for producing a copolymer of a non-polar olefin and a polar olefin and the copolymer obtained thereby
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1170308A2

  公开（公告）日：2002-01-09

  A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M' is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is -O-, -Si-, -Se-, -N(R6)-, n is a number satisfying a valence of M', R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

  一种生产极性烯烃共聚物的工艺，包括在选自元素周期表第 4、5、6 和 11 族的过渡金属化合物存在下，使非极性烯烃和极性烯烃共聚，该过渡金属化合物由下式(IV)表示： 其中 M' 是选自元素周期表第 4、5、6 和 11 族的过渡金属原子，m 是 1 至 6 的整数，A 是-O-、-Si-、-Se-、-N(R6)-，n 是满足 M' 的价数，R1 至 R4 和 R6 各为氢原子、卤素原子、烃基等、X 是卤素原子、氧原子、烃基等，以及至少一种选自有机金属化合物（B-1）、有机铝氧 化物（B-2）和离子电离化合物（B-3）的化合物（B）。因此，该工艺能够在温和的聚合条件下获得性能优异的极性烯烃共聚物。
• CATALYSTS FOR OLEFIN POLYMERIZATION, PROCESS FOR PRODUCTION OF OLEFIN POLYMERS, OLEFIN COPOLYMERS, NOVEL TRANSITION METAL COMPOUNDS, AND PROCESS FOR PRODUCTION OF TRANSITION METAL COMPOUNDS
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1788002A1

  公开（公告）日：2007-05-23

  [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties. [Construction] A catalyst for olefin polymerization comprising(A) a transition metal compound represented by the following general formula (1); and (B) at least one compound selected from the group consisting of (B-1) organometallic compound, (B-2) organoaluminum oxy compound and (B-3) compounds capable of reacting with the transition metal compound (A) to form an ion pair: (M is a transition metal atom selected from Groups 4 to 6 of the periodic table; the two of R1 to R4, which are adjacent to each other, are combined to form a ring with the carbon atoms to which the two are bonded; groups of not forming a ring, R5 to R8, and X are each an atom or a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing group, and a nitrogen-containing group; Q is -O-, -S-, -NRa-, or -PRb- (Ra and Rb are each a hydrogen atom or a hydrocarbon group); Y is a neutral ligand having an electron-donating group; m is a number satisfying the valence of M; and n is an integer of 0 to 3.).

  [任务]提供一种烯烃聚合催化剂，该催化剂具有优异的烯烃聚合性能，并能生产出性能优异的聚烯烃。 [结构]一种用于烯烃聚合的催化剂，包括（A）由以下通式（1）表示的过渡金属化合物；和（B）至少一种选自（B-1）有机金属化合物、（B-2）有机铝氧化合物和（B-3）能与过渡金属化合物（A）反应形成离子对的化合物组成的组的化合物： (M是选自元素周期表第 4 至第 6 族的过渡金属原子；R1 至 R4 中相邻的两个结合在一起，与二者结合的碳原子形成环；不形成环的基团 R5 至 R8 和 X 各是一个原子或一个选自氢原子、卤素原子、烃基、卤代烃基、含氧基和含氮基的基团；Q是-O-、-S-、-NRa-或-PRb-（Ra和Rb各自是氢原子或烃基团）；Y是具有电子供体的中性配体；m是满足M的价数；n是0至3的整数。).
• COPOLYMER OF OLEFIN AND CONJUGATED DIENE, AND PROCESS FOR PRODUCING SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2415792A1

  公开（公告）日：2012-02-08

  An object of the invention is to provide copolymers which have a double bond in a side chain and are substantially free of unsaturated bonds in the main chain, copolymers which have a cyclic structure and are substantially free of unsaturated bonds in the main chain, and processes for economically synthesizing these copolymers. A copolymer of the invention is obtained by copolymerizing at least ethylene and a conjugated diene. In the copolymer, structural units derived from the conjugated diene represent 1 to 90 mol%. Structural units resulting from 1,2-addition of the conjugated diene and having a side-chain double bond represent 0 to 90 mol%, structural units resulting from 1, 4-addition of the conjugated diene represent 0 to 3 mol%, structural units resulting from 1, 3-addition of the conjugated diene represent 0 to 3 mol%, and the total of structural units resulting from 1,2-addition of the conjugated diene and having a 1,2-cyclopropane skeleton and structural units resulting from 1,2-addition of the conjugated diene and having a 1,2-cyclopentane skeleton represent 4 to 100 mol%.

  本发明的目的是提供侧链中有双键而主链中基本上没有不饱和键的共聚物、具有环状结构而主链中基本上没有不饱和键的共聚物以及经济地合成这些共聚物的工艺。 本发明的共聚物至少是由乙烯和共轭二烯共聚而成。在共聚物中，共轭二烯产生的结构单元占 1 至 90 摩尔%。共轭二烯的 1，2-加成并具有侧链双键的结构单元占 0 至 90 摩尔%，共轭二烯的 1，4-加成结构单元占 0 至 3 摩尔%，共轭二烯的 1，3-加成结构单元占 0 至 3 摩尔%、由共轭二烯的 1，2-加成产生的具有 1，2-环丙烷骨架的结构单元和由共轭二烯的 1，2-加成产生的具有 1，2-环戊烷骨架的结构单元的总和占 4 至 100 摩尔%。