N,N'-Di(butan-2-yl)hexane-1,6-diamine | 78987-86-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-Di(butan-2-yl)hexane-1,6-diamine
• 英文别名: N,N'-di-sec-butyl-hexanediyldiamine；N,N'-Di-sec-butyl-hexandiyldiamin；N,N'-bis(1-methylpropyl)-1,6-hexanediamine；N,N'-di-sec-butyl-1,6-diaminohexane
• CAS: 78987-86-7
• 化学式: C₁₄H₃₂N₂
• 分子量: 228.421
• InChiKey: QKRHUNNQVRLNBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-[1-Methyl-prop-(Z)-ylidene]-N'-[1-methyl-prop-(E)-ylidene]-hexane-1,6-diamine; compound with acetic acid 在 magnesium 、 溶剂黄146 作用下， 以 甲醇 为溶剂， 生成 N,N'-Di(butan-2-yl)hexane-1,6-diamine
  参考文献：
  名称：

  金属镁还原胺化制备仲胺

  摘要：

  已经开发了通过用伯胺还原胺化羰基化合物来制备仲胺的新颖而有效的方法。还原反应是利用三乙胺-乙酸作为缓冲液，用甲醇中的金属镁完成的，得到的纯仲胺大部分收率很高（65-80％）。没有观察到叔胺或醇的形成。使用乙酸铵作为氨基组分以适度的产率（约50％）得到伯胺，以及可变量的仲胺。烯胺未经历还原。该方法便宜，相对快速，操作简单并且适用于大规模制备。另外，已经开发了一种从仲胺中分离伯胺的简单方法。

  DOI：

  10.1039/p19960000265

文献信息

• Diimines and secondary diamines
  申请人：Lee Y. John

  公开号：US20060217567A1

  公开（公告）日：2006-09-28

  This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

  这项发明提供了具有至少两个碳原子的亚烷基亚胺基团的芳香二亚胺和具有至少两个碳原子的氨基亚烷基团的芳香二胺。这些芳香二亚胺和芳香二胺可以是一个苯环的形式，也可以是由烷基桥连接的两个苯环的形式；每个邻位对着亚烷基基团或氨基基团。当以一个苯环的形式时，环上有两个亚胺基团或两个氨基团；亚胺基团或氨基团互为间位或对位。当以由烷基桥连接的两个苯环的形式时，每个苯环上要么有一个亚胺基团，要么有一个氨基基团。还提供了形成二亚胺和二胺的方法。
• DIIMINES AND SECONDARY DIAMINES
  申请人：Lee Y. John

  公开号：US20080033210A1

  公开（公告）日：2008-02-07

  This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

  本发明提供了具有至少两个碳原子的亚胺烃基亚胺基的芳香族二亚胺和具有至少两个碳原子的氨基烃基氨基的芳香族二级二胺。芳香族二亚胺和芳香族二级二胺均为一个苯环的形式或由一个烷基桥连接的两个苯环的形式；每个对位于亚胺基或氨基的位置都带有一个烃基基团。当为一个苯环的形式时，环上有两个亚胺基或两个氨基；亚胺基或氨基相对于彼此是间位或对位的。当为由一个烷基桥连接的两个苯环的形式时，每个苯环上有一个亚胺基或一个氨基。还提供了形成二亚胺和二级二胺的方法。
• Diimines and Secondary Diamines
  申请人：Lee John Y.

  公开号：US20080194788A1

  公开（公告）日：2008-08-14

  This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and in which each position ortho to an amino group bears a hydrocarbyl group. Also provided are processes for forming diimines and secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of the invention.

  本发明提供了芳香二亚胺，其中二亚胺具有至少两个碳原子的亚胺基，并且可以是具有一个苯环的形式，在该苯环上具有两个亚胺基，这些亚胺基互为间位或对位，并且在每个与亚胺基相邻的位置上带有一个烃基团，或者是由一个烷基桥连接的两个苯环的形式，并且在每个与亚胺基相邻的位置上带有一个烃基团。本发明还提供了芳香二级二胺，其中二胺具有至少两个碳原子的氨基烃基团，并且可以是具有一个苯环的形式，在该苯环上具有两个氨基团，这些氨基团互为间位或对位，并且在每个与氨基团相邻的位置上带有一个烃基团，或者是由一个烷基桥连接的两个苯环的形式，并且在每个与氨基团相邻的位置上带有一个烃基团。本发明还提供了从一级二胺制备二亚胺和二级二胺的方法，包括本发明的芳香二亚胺和芳香二级二胺。
• Secondary diamine
  申请人：Albemarle Corporation

  公开号：EP2143707A2

  公开（公告）日：2010-01-13

  This invention provides an aliphatic secondary diamine which is N,N'-di-(3,3-dimethyl-2-butyl)-1,6-diaminohexane, and a chain extender which comprises N,N'-di-(3,3-dimethyl-2-butyl)-1,6-diaminohexane and a mixture of 2,4-diethyl-6-methyl-1,3-benzenediamine and 4,6-diethyl-2-methyl-1,3-benzenediamine.

  本发明提供了一种脂肪族仲二胺，它是 N,N'-二-(3,3-二甲基-2-丁基)-1,6-二氨基己烷，以及一种扩链剂，它包括 N,N'-二-(3,3-二甲基-2-丁基)-1,6-二氨基己烷和 2,4-二乙基-6-甲基-1,3-苯二胺与 4,6-二乙基-2-甲基-1,3-苯二胺的混合物。
• POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND APPLICATION FOR SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3168246A1

  公开（公告）日：2017-05-17

  Provided is a polymerizable composition for an optical material including (A) an amine having two or more secondary amino groups, (B) an isocyanate having two or more isocyanato groups, and (C) a thiol having three or more mercapto groups, in which the ratio (a/b) of the molar number a of amino groups in the amine (A) with respect to the molar number b of isocyanato groups in the isocyanate (B) is in the range of 0.10 to 0.60.

  本发明提供了一种用于光学材料的可聚合组合物，包括 (A) 具有两个或两个以上仲氨基的胺，(B) 具有两个或两个以上异氰酸酯基团的异氰酸酯，以及 (C) 具有三个或三个以上巯基的硫醇，其中胺 (A) 中氨基的摩尔数 a 与异氰酸酯 (B) 中异氰酸酯基团的摩尔数 b 之比 (a/b) 在 0.10 至 0.60 之间。

表征谱图