2,5-bis(2-methylprop-2-enoyloxy)benzoic Acid | 574002-50-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5-bis(2-methylprop-2-enoyloxy)benzoic Acid
• CAS: 574002-50-9
• 化学式: C₁₅H₁₄O₆
• 分子量: 290.27
• InChiKey: SVMANJSNQHAWNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  89.9
• 氢给体数：
  1
• 氢受体数：
  6

文献信息

• Phthalate polymers
  申请人：Huang Wenxi

  公开号：US20060183242A1

  公开（公告）日：2006-08-17

  Polymers bearing metal chelating groups are readily prepared from easily accessible precursors. The polymers are readily converted to the corresponding metal chelates. The polymers can also include an energy absorbing moiety for use in matrix assisted laser desorption/ionization mass spectrometry. The polymer can also include a photo-curable group, which can be used to form cross-links within the bulk polymer or between the polymer and a surface functionalized with a polymerizable moiety. The polymers are incorporated into devices of use for the analysis, capture, separation, or purification of an analyte. In an exemplary embodiment, the invention provides a substrate coated with a polymer of the invention, the substrate being adapted for use as a probe for a mass spectrometer.

  含有金属螯合基团的聚合物可以轻松地从易得到的前体制备而成。这些聚合物可以轻松地转化为相应的金属螯合物。聚合物还可以包括用于基质辅助激光解吸/电离质谱的能量吸收基团。聚合物还可以包括光固化基团，可用于在体积聚合物内或在表面功能化为聚合物的基团之间形成交联。这些聚合物被纳入用于分析、捕获、分离或纯化分析物的设备中。在一个示例实施方案中，本发明提供了一种用本发明的聚合物涂层的基板，该基板适用于作为质谱仪的探针。
• Zwitterionic polymers
  申请人：Huang Wenxi

  公开号：US20060183863A1

  公开（公告）日：2006-08-17

  Zwitterionic polymers bearing positive and negative charges are readily prepared from easily accessible precursors. The polymers show enhanced binding affinities for analytes under high salt conditions, compared to similar polymers bearing a charge of a single polarity. The polymers can also include an energy absorbing moiety for use in matrix assisted laser desorption/ionization mass spectrometry. The polymer can also include a photo-curable group, which can be used to form cross-links within the bulk polymer or between the polymer and a surface functionalized with a polymerizable moiety. The polymers are incorporated into devices of use for the analysis, capture, separation, or purification of an analyte. In an exemplary embodiment, the invention provides a substrate coated with a polymer of the invention, the substrate being adapted for use as a probe for a mass spectrometer.

  带正负电荷的离子聚合物可以从易于获取的前体中轻松制备。与带单极性电荷的类似聚合物相比，这些聚合物在高盐条件下对分析物的结合亲和力增强。聚合物还可以包含能量吸收基团，用于基质辅助激光解析/电离质谱。聚合物还可以包含光固化基团，可用于在体积聚合物内或在具有可聚合基团的表面与聚合物之间形成交联。这些聚合物被纳入用于分析、捕获、分离或纯化分析物的设备中。在一个示例实施例中，本发明提供了一种涂有本发明聚合物的基底，该基底适用于作为质谱仪的探针。
• CHELATING MONOMERS AND POLYMERS
  申请人：Zhang Hongmin

  公开号：US20070254378A1

  公开（公告）日：2007-11-01

  This invention provides chelating moieties that comprise an aryl group. Monomers that include the chelating moieties can be polymerized into chelating polymers. Chelating polymers are useful to chelate metals. Chelating polymers in the form of metal chelates are useful for binding analytes, such as polypeptides that comprise histidine residues. Chelating polymers can be includes in articles such as chips and chromatographic materials.

  本发明提供了包含芳基的螯合基团。包括螯合基团的单体可以聚合成螯合聚合物。螯合聚合物可用于螯合金属。以金属螯合物形式的螯合聚合物可用于结合分析物，例如包含组氨酸残基的多肽。螯合聚合物可以包含在芯片和色谱材料等物品中。
• Monomers and polymers having energy absorbing moieties of use in desorption/ionization of analytes
  申请人：Ciphergen Biosystems, Inc.

  公开号：US20030207462A1

  公开（公告）日：2003-11-06

  The present invention provides polymerizable monomers that incorporate moieties derived from energy absorbing molecules (EAM). The invention also provides polymers that are based on the monomers. The polymers have unique properties that make them ideally suited for use in diverse analyses, including desorption/ionization mass spectrometry of analytes. The invention also provides a device that incorporates the polymeric compositions of the inventions, methods of using the device to detect, quantify and identify analytes, and a method of preparing a device of the invention.

  本发明提供了含有源自能量吸收分子（EAM）的分子的可聚合单体。本发明还提供了基于这些单体的聚合物。这些聚合物具有独特的性质，非常适合用于各种分析，包括分析物的解吸/电离质谱分析。本发明还提供了一种包含本发明聚合物组合物的装置，使用该装置检测、量化和鉴定分析物的方法，以及制备本发明装置的方法。
• MONOMERS AND POLYMERS HAVING ENERGY ABSORBING MOIETIES OF USE IN DESORPTION/IONIZATION OF ANALYTES
  申请人：Ciphergen Biosystems, Inc.

  公开号：EP1481244A2

  公开（公告）日：2004-12-01