3-[3-(三氟甲基)吡唑-1-基]吡啶 | 588717-60-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 3-[3-(三氟甲基)吡唑-1-基]吡啶
• 英文名称: 3-(3-(trifluoromethyl)-1H-pyrazol-1-yl)pyridine
• 英文别名: Pyridine, 3-[3-(trifluoromethyl)-1H-pyrazol-1-yl]-；3-[3-(trifluoromethyl)pyrazol-1-yl]pyridine
• CAS: 588717-60-6
• 化学式: C₉H₆F₃N₃
• 分子量: 213.162
• InChiKey: ZRDYPNPOVQTYPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-(三氟甲基)-1H-咪唑 、 吡啶-3-硼酸 在 吡啶 、 copper diacetate 作用下， 以 二氯甲烷 为溶剂， 以59%的产率得到3-[3-(三氟甲基)吡唑-1-基]吡啶
  参考文献：
  名称：

  Copper promoted CN and CO bond cross-coupling with phenyl and pyridylboronates

  摘要：

  Acyclic and cyclic esters, as well as anhydride (boroxine) of phenylboronic acids are efficient phenylating agents in copper promoted C-N and C-O bond cross-coupling reactions. The first successful C-N cross-coupling of a heterocyclic boronate with heteroarenes, such as indazole, has been demonstrated. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00739-1

文献信息

• Pesticidal Compositions and Processes Related Thereto
  申请人：Yap Maurice C.H.

  公开号：US20120110702A1

  公开（公告）日：2012-05-03

  This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

  这份文件公开了具有以下公式（“公式一”）的分子以及与之相关的过程。
• PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO
  申请人：DOW AGROSCIENCES LLC

  公开号：US20130288893A1

  公开（公告）日：2013-10-31

  This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

  这份文件公开了具有以下公式（“公式一”）的分子以及与之相关的过程。
• Pesticidal compositions and processes related thereto
  申请人：Dow AgroSciences LLC

  公开号：US10165775B2

  公开（公告）日：2019-01-01

  This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

  本文件公开了具有以下公式（"公式一"）的分子： 及其相关工艺。
• Emissive transition-metal complexes with both carbon-phosphorus ancillary and chromophoric chelates, synthetic method of preparing the same and phosphorescent organic light emitting diode thereof
  申请人：Chi Yun

  公开号：US20090209756A1

  公开（公告）日：2009-08-20

  The present invention discloses a phosphorescent tris-chelated transition metal complex comprising i) two identical carbon-nitrogen (ĈN) or nitrogen-nitrogen (N̂N) chromophoric ligands being incorporated into a coordination sphere thereof with a transition metal, and one carbon-phosphorus (ĈP) chelate being incorporated into the coordination sphere; or ii) one carbon-nitrogen (ĈN) or nitrogen-nitrogen (N̂N) chromophoric ligand forming a coordination sphere thereof with a transition metal, and two identical carbon-phosphorus (ĈP) chelates being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the chromophoric ligands possess a relatively lower energy gap in comparison with that of the non-chromophoric chelate, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that bright phosphorescence can be observed. The architecture and energy gap of the present molecular designs are suitable for generation of high efficiency blue, green and even red emissions.
• EMISSIVE TRANSITION-METAL COMPLEXES WITH BOTH CARBON-PHOSPHORUS ANCILLARY AND CHROMOPHORIC CHELATES, SYNTHETIC METHOD OF PREPARING THE SAME AND PHOSPHORESCENT ORGANIC LIGHT EMITTING DIODE THEREOF
  申请人：CHI Yun

  公开号：US20130005975A1

  公开（公告）日：2013-01-03

  The present invention provides a phosphorescent tris-chelated transition metal complex having one carbon-nitrogen (ĈN) or nitrogen-nitrogen (N̂N) chromophoric ligand forming a coordination sphere thereof with a transition metal, and two identical carbon-phosphorus (ĈP) chelates being incorporated into the coordination sphere, wherein the metal is iridium, platinum, osmium or ruthenium, and the chromophoric ligands possess a relatively lower energy gap in comparison with that of the non-chromophoric chelate, the latter afforded an effective barrier for inhibiting the ligand-to-ligand charge transfer process, so that bright phosphorescence can be observed. The architecture and energy gap of the present molecular designs are suitable for generation of high efficiency blue, green and even red emissions.