3-[4-[2-[4-(3-丙-2-烯酰基氧基丙氧基)苯基]丙-2-基]苯氧基]丙基丙-2-烯酸酯 | 51989-01-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-[4-[2-[4-(3-丙-2-烯酰基氧基丙氧基)苯基]丙-2-基]苯氧基]丙基丙-2-烯酸酯
• 中文别名: 十五烷酸异丙酯
• 英文名称: (1-Methylethylidene)bis(4,1-phenyleneoxy-3,1-propanediyl) diacrylate
• 英文别名: 3-[4-[2-[4-(3-prop-2-enoyloxypropoxy)phenyl]propan-2-yl]phenoxy]propyl prop-2-enoate
• CAS: 51989-01-6
• 化学式: C₂₇H₃₂O₆
• 分子量: 452.5
• InChiKey: LKJTVGPNIFDNOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  33
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• GAS-BARRIER FILM, AND METHOD FOR SEALING DISPLAY DEVICE WITH GAS-BARRIER FILM
  申请人：TSUKAHARA Jiro

  公开号：US20090061223A1

  公开（公告）日：2009-03-05

  Disclosed is A gas barrier film comprising a substrate film and a barrier layer containing an organic region and an inorganic region on the substrate film, in which, when the organic region is provided on one surface of the gas barrier film, the outermost layer on the side with the organic region is an adhesive layer, or when the organic regions are provided on both surfaces of the gas barrier film, at least one outermost layer of the gas barrier film is an adhesive layer. The gas barrier film is capable of simplifying the working process with it and keeping its good gas-barrier property.

  本发明涉及一种气体阻隔薄膜，包括基材薄膜和位于基材薄膜上的含有有机区域和无机区域的阻隔层，其中，当有机区域位于气体阻隔薄膜的一侧时，有机区域所在侧的最外层为粘合层；或者当有机区域位于气体阻隔薄膜的两侧时，气体阻隔薄膜至少有一侧的最外层为粘合层。该气体阻隔薄膜能够简化使用过程并保持其良好的气体阻隔性能。
• Scratch-resistant, dyeable coating compositions for synthetic resin articles
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0012948A1

  公开（公告）日：1980-07-09

  Coating compositions comprising a polyfunctional monomer of a mono or polypentaerythritol poly(meth)acrylate, a bifunctional (meth)acrylate having specific monomer structure, an additional (meth)acrylate containing not more than 2 (meth)acryloyloxy groups, a phosphoric acid ester and an ethanolamine all blended together in a suitable organic solvent system together with a photosensitizer are disclosed. The compositions provide a scratch-resistant, hard cross-linked film surface that is dyeable and resists static and fogging to a synthetic resin article, such as polymethyl methacrylate, to which they are applied.

  本发明公开了一种涂料组合物，该组合物由单或多季戊四醇聚（甲基）丙烯酸酯的多官能团单体、具有特定单体结构的双官能团（甲基）丙烯酸酯、含有不超过 2 个（甲基）丙烯酰氧基的另一种（甲基）丙烯酸酯、磷酸酯和乙醇胺在适当的有机溶剂体系中与光敏剂混合而成。这些组合物可为合成树脂制品（如聚甲基丙烯酸甲酯）提供耐刮擦的硬交联薄膜表面，该表面可染色、抗静电和防雾。
• PHOTO-POLYMERIZABLE LIGHT-SENSITIVE RESIN COMPOSITION AND LIGHT-SENSITIVE SHEET MATERIAL
  申请人：ARAI, Tokuji

  公开号：EP0035574A1

  公开（公告）日：1981-09-16

  Photo-polymerizable light-sensitive resin composition containing a styrene/ maleic acid copolymer resin, an ethylenically unsaturated compound, and a photo-polymerization initiator. A light-sensitive sheet comprising support (10) having a layer (11) of said photo-polymerizable light-sensitive resin composition is also disclosed. The composition and the sheet material can be advantageously used particularly for preparing various cards such as credit cards and cash cards.

  可光聚合光敏树脂组合物，含有苯乙烯/马来酸共聚物树脂、乙烯基不饱和化合物和光聚合引发剂。 还公开了一种光敏片材，包括具有所述可光聚合光敏树脂组合物层（11）的支撑物（10）。 该组合物和片材尤其可用于制作各种卡片，如信用卡和现金卡。
• Coating composition and process for preparing synthetic resin shaped articles by using same
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0035272A1

  公开（公告）日：1981-09-09

  A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer composition comprising (i) 40-100 wt.% of a polyfunctional monomer containing at least three methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 900 and (ii) 0-60 wt.% of a mono- or bi-functional monomer having one or two methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 300 per methacryloyloxy or acryloyloxy group, (b) 5-35 parts by wt., based on 100 wt. parts of the monomer composition, of at least one ultraviolet absorber, (c) 0.5-8 wt. parts, based on 100 parts by wt. of the monomer composition, of at least one polymeric material selected from polymers of alkyl methacrylates and alkyl acrylates, and (d) 0.01-6 parts by wt., based on 100 parts by wt. of the monomer composition, of a photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with ultraviolet rays in an inert gas or air to form a cross-linked coating film having a thickness of 1 to 30 microns.

  本文介绍了一种用于制备具有优异耐磨性和耐候性的合成树脂成型品的涂层组合物。这种组合物包括 (a) 多官能团单体组合物，包括：(i) 40-100 重量份的多官能团单体，其分子中至少含有三个甲基丙烯酰氧基或丙烯酰氧基基团，且分子量不高于约 900；(ii) 0-60 重量份的单官能团或双官能团单体，其分子中含有一个或两个甲基丙烯酰氧基或丙烯酰氧基基团，且每个甲基丙烯酰氧基或丙烯酰氧基基团的分子量不高于约 300、 (b) 以 100 重量份的单体组合物计，5-35 重量份的至少一种紫外线吸收剂、 (c) 以 100 重量份的单体组合物为基准，0.5-8 重量份的至少一种选自烷基 甲基丙烯酸酯和烷基丙烯酸酯聚合物的聚合材料，以及 (d) 以 100 份单体组合物重量计，0.01-6 份光敏剂。将涂层组合物涂在合成树脂成型品上，然后在惰性气体或空气中用紫外线照射，形成厚度为 1 至 30 微米的交联涂膜。
• Method and apparatus for surface-hardening treatment of synthetic resin shaped articles
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0071235A2

  公开（公告）日：1983-02-09

  Method and apparatus for the surface-hardening treatment of a synthetic resin shaped article is provided, wherein the shaped article is dipped in a surface-hardening solution; the shaped article is gradually pulled up therefrom thereby to be coated with the surface-hardening solution; and the coated article is irradiated with ultraviolet rays to cure the coating. The shaped article (22) is dipped in succession in a washing tank (8), a drying tank (7) having warm water or an organic solvent and a hardening solution tank (6) while the shaped article (22) is conveyed by a first conveyor (1), and then, the shaped article (22) is transferred from the first conveyor (1) through an intermediate conveyor (2) to a second conveyor (3) whereby the shaped article (22) is conveyed to an ultraviolet ray-curing step (15). The shaped article (22) is introduced to and withdrawn from the respective steps in the state where the shaped article is hung on a hanger (4, 5), and one or a plurality of hangers are attached to each of a plurality of portions of the first conveyor (1) so that the shaped articles (22) are simultaneously subjected to the dipping treatment in the respective tanks, whereas the hangers are conveyed one by one from the intermediate conveyor (2) to the second conveyor (3) where the shaped articles (22) are separately hung. In each of the tanks (6, 7, 8), organic solvent and the hardening solution tank (6), the liquid is overflowed therefrom and circulated via a filter (33, 32, 31) to each tank. The surface-hardening treatment is carried out under such conditions that the hardening solution and the atmosphere above the hardening solution tank (6) are maintained at room temperature and the dew point of said atmosphere is maintained at least 3°C lower than the temperature of the hardening solution.

  本发明提供了对合成树脂异型制品进行表面硬化处理的方法和设备，其中将异型制品浸入表面硬化溶液中；将异型制品逐渐拉起，从而涂上表面硬化溶液；用紫外线照射被涂物，使涂层固化。定型物品（22）在第一传送带（1）的输送下依次浸入清洗槽（8）、装有温水或有机溶剂的干燥槽（7）和硬化溶液槽（6），然后，定型物品（22）从第一传送带（1）通过中间传送带（2）传送到第二传送带（3），定型物品（22）被传送到紫外线固化步骤（15）。定型物品（22）在挂在衣架（4、5）上的状态下被送入并从相应的步骤中取出，一个或多个衣架被连接到第一传送带（1）的多个部分中的每一部分上，以便定型物品（22）同时在相应的槽中进行浸渍处理，而衣架则一个接一个地从中间传送带（2）传送到第二传送带（3），定型物品（22）分别挂在第二传送带（3）上。在每个槽（6、7、8）、有机溶剂槽和硬化溶液槽（6）中，液体从其中溢出并通过过滤器（33、32、31）循环到每个槽中。表面硬化处理是在这样的条件下进行的：硬化溶液和硬化溶液槽（6）上方的大气保持室温，所述大气的露点比硬化溶液的温度至少低 3°C。