Methyl bis[(pyrrolidine-1-carbothioyl)sulfanyl]acetate | 64394-69-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: Methyl bis[(pyrrolidine-1-carbothioyl)sulfanyl]acetate
• 英文别名: methyl 2,2-bis(pyrrolidine-1-carbothioylsulfanyl)acetate
• CAS: 64394-69-0
• 化学式: C₁₃H₂₀N₂O₂S₄
• 分子量: 364.6
• InChiKey: KKTNHQBVFHNKCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  148
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• Polymeric material and methods of making using controlled radical initiators
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10400055B2

  公开（公告）日：2019-09-03

  Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, and polymeric materials formed from the reaction mixtures are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds with a single carbon atom between the two dithiocarbamate or dithiocarbonate groups. Polymeric materials such as homopolymers, random copolymers, and block copolymers can be prepared using the controlled radical initiators.

  提供了受控自由基引发剂、含有受控自由基引发剂和各种乙烯不饱和单体的反应混合物，以及由反应混合物形成的聚合物材料。受控自由基引发剂是双二硫代氨基甲酸酯或双二硫代碳酸酯化合物，在两个二硫代氨基甲酸酯或二硫代碳酸酯基团之间有一个碳原子。使用受控自由基引发剂可以制备均聚物、无规共聚物和嵌段共聚物等聚合物材料。
• Crosslinkable and crosslinked polymeric materials
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10640686B2

  公开（公告）日：2020-05-05

  Crosslinkable compositions are provided that contain a) a polymeric material having at least two terminal dithiocarbamate groups or two terminal dithiocarbonate groups and b) a monomer composition that includes at least a crosslinking monomer having two or more ethylenically unsaturated groups. The polymeric materials in the crosslinkable compositions undergo chain extension and crosslinking reactions when exposed to actinic radiation in the ultraviolet region of the electromagnetic spectrum. Additionally, crosslinked compositions, articles that contain the crosslinkable compositions or the crosslinked compositions, and methods of making the articles are provided.

  可交联组合物包含 a) 具有至少两个末端二硫代氨基甲酸酯基团或两个末端二硫代碳酸酯基团的聚合材料和 b) 单体组合物，该单体组合物至少包括具有两个或两个以上乙烯基不饱和基团的交联单体。可交联组合物中的聚合材料在暴露于电磁波谱紫外区的光辐射时会发生链延伸和交联反应。此外，还提供了交联组合物、含有可交联组合物或交联组合物的物品以及制造这些物品的方法。
• CROSSLINKABLE AND CROSSLINKED POLYMERIC MATERIALS
  申请人：3M Innovative Properties Company

  公开号：EP3559062B1

  公开（公告）日：2020-12-02
• POLYMERIC MATERIAL AND METHODS OF MAKING USING CONTROLLED RADICAL INITIATORS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20190153142A1

  公开（公告）日：2019-05-23

  Controlled radical initiators, reaction mixtures containing the controlled radical initiators and various ethylenically unsaturated monomers, and polymeric materials formed from the reaction mixtures are provided. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds with a single carbon atom between the two dithiocarbamate or dithiocarbonate groups. Polymeric materials such as homopolymers, random copolymers, and block copolymers can be prepared using the controlled radical initiators.