ethyl-dodecyl-methyl sulfonium ; iodide | 65955-45-5

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: ethyl-dodecyl-methyl sulfonium ; iodide
• 英文别名: Aethyl-dodecyl-methyl-sulfonium; Jodid；Dodecyl(ethyl)methylsulfanium iodide；dodecyl-ethyl-methylsulfanium;iodide
• CAS: 65955-45-5
• 化学式: C₁₅H₃₃S*I
• 分子量: 372.398
• InChiKey: ARJMGEOMIVYGLN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.18
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  溴代十二烷 在 甲醇 、 乙醇 、 水 作用下， 生成 ethyl-dodecyl-methyl sulfonium ; iodide
  参考文献：
  名称：

  The Synthesis of Certain Trisaccharides and a Study of their Behavior in Alkaline Solution^1,2

  摘要：

  DOI：

  10.1021/ja01864a030

文献信息

• Molten and Solid Trialkylsulfonium Iodides and Their Polyiodides as Electrolytes in Dye-Sensitized Nanocrystalline Solar Cells
  作者：Heléne Paulsson、Anders Hagfeldt、Lars Kloo

  DOI：10.1021/jp036859v

  日期：2003.12.1

  Potential new electrolytes for dye-sensitized nanocrystalline solar cells (DNSCs) of Gratzel type based on trialkylsulfonium iodides have been investigated. Room temperature molten salts of (Et2MeS)I, (Bu2MeS)I, and (Bu2EtS)I, with iodine in low concentrations, revealed good conducting abilities. DNSCs using iodine-doped (Bu2MeS)l as electrolyte achieved an overall light-to-electricity conversion efficiency of 3.7% in simulated AM 1.5 solar light at a light intensity of 0.1 Sun. The effects from varying the temperature during the IN measurements were studied, as well as the effects of 4-tert-butylpyridine treatment of the electrodes.
• The Synthesis of Certain Trisaccharides and a Study of their Behavior in Alkaline Solution^1,2
  作者：Samuel H. Nichols、Wm. Lloyd Evans、Harold D. McDowell

  DOI：10.1021/ja01864a030

  日期：1940.7