6,6'-bis-(4-t-butylbenzoylamino)-2,2'-bipyridine | 192193-79-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6,6'-bis-(4-t-butylbenzoylamino)-2,2'-bipyridine
• 英文别名: N,N'-([2,2'-Bipyridine]-6,6'-diyl)bis(4-(tert-butyl)benzamide)；4-tert-butyl-N-[6-[6-[(4-tert-butylbenzoyl)amino]pyridin-2-yl]pyridin-2-yl]benzamide
• CAS: 192193-79-6
• 化学式: C₃₂H₃₄N₄O₂
• 分子量: 506.648
• InChiKey: QLEOQVZSJDXISF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  38
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6,6'-bis-(4-t-butylbenzoylamino)-2,2'-bipyridine 、 cobalt(II) diacetate tetrahydrate 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Dioxygen adducts of cobalt(II) complexes of 6,6′-bis(p-substituted benzoylamino)-2,2′-bipyridines and their catalytic activities in oxygenation of 2,6-di-tert-butylphenol

  摘要：

  The oxygen affinities and properties of oxygen adducts of complexes [CoL] [H-2L = 6,6'-bis(benzoyl-amino)-2,2'-bipyridine and its 4-methyl-, -tert-butyl or -chloro-benzoylamino analogues] has been studied by cyclic voltammetry and IR, electronic and ESR spectroscopy. The complexes exhibited oxygen-binding ability in the presence of an appropriate axial base ligand (B), and the oxygen adducts were of the end-on bonded Co(III) (O2) type [CoL(B)(O2)]. More complete electron transfer from the metal centre to the oxygen was indicated compared to that with [Co(salen)] [H-2salen = N,N'-ethylenebis(salicylideneimine)]. Electron-donating substituents gave higher concentrations of the oxygen adducts. The superior catalytic activity of these complexes, especially the Me- and Bu(t)-substituted derivatives, in the oxygenation of 2,6-di-tert-butylphenol to the corresponding quinone is interpreted in terms of the reactivity of the co-ordinated oxygen and the oxygen affinity of the complexes.

  DOI：

  10.1039/dt9930003647

文献信息

• Dioxygen adducts of cobalt(<scp>II</scp>) complexes of 6,6′-bis(p-substituted benzoylamino)-2,2′-bipyridines and their catalytic activities in oxygenation of 2,6-di-tert-butylphenol
  作者：Koji Araki、Takashi Kuboki、Makihiro Otohata、Nobuyuki Kishimoto、Masaki Yamada、Shinsaku Shiraishi

  DOI：10.1039/dt9930003647

  日期：——

  The oxygen affinities and properties of oxygen adducts of complexes [CoL] [H-2L = 6,6'-bis(benzoyl-amino)-2,2'-bipyridine and its 4-methyl-, -tert-butyl or -chloro-benzoylamino analogues] has been studied by cyclic voltammetry and IR, electronic and ESR spectroscopy. The complexes exhibited oxygen-binding ability in the presence of an appropriate axial base ligand (B), and the oxygen adducts were of the end-on bonded Co(III) (O2) type [CoL(B)(O2)]. More complete electron transfer from the metal centre to the oxygen was indicated compared to that with [Co(salen)] [H-2salen = N,N'-ethylenebis(salicylideneimine)]. Electron-donating substituents gave higher concentrations of the oxygen adducts. The superior catalytic activity of these complexes, especially the Me- and Bu(t)-substituted derivatives, in the oxygenation of 2,6-di-tert-butylphenol to the corresponding quinone is interpreted in terms of the reactivity of the co-ordinated oxygen and the oxygen affinity of the complexes.