癸基己基邻苯二甲酸酯 | 25724-58-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 癸基己基邻苯二甲酸酯
• 英文名称: Decyl hexyl phthalate
• 英文别名: 2-O-decyl 1-O-hexyl benzene-1,2-dicarboxylate
• CAS: 25724-58-7
• 化学式: C₂₄H₃₈O₄
• 分子量: 390.6
• InChiKey: OMQBXAQAHHFSST-UHFFFAOYSA-N

物化性质

• 沸点：
  417.28°C (rough estimate)
• 密度：
  0.9966 (rough estimate)
• 溶解度：
  可溶于氯仿、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  28
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Modified silane compounds
  申请人：——

  公开号：US20040087803A1

  公开（公告）日：2004-05-06

  This invention relates to the reversible protection of hydroxy-silane functional groups by acid cleavable protecting groups. The development of reversible protecting groups greatly enhances the current utility of silanes while introducing further novel applications. For instance, reversibly protected silanes are of particular value in applications where room temperature cure and/or adhesion is of value, such as coatings, high resolution imaging, caulks, adhesives, sealents, gaskets, and silicones. Reversibly protected silanes can also be beneficially used in reticulating agents, and in sizing agents, tires, and release coatings. The incorporation of reversibly protected silanes into coating resins is of particular value. The reversibly protected silane can be incorporated into the coating resin by polymerizing a monomer containing the reversibly protected silane into the resin or by post-addition into the coating formulation. The reversibly protected silane remains protected under basic conditions, such as in a coating formulation that contains a volatile base, for instance ammonium hydroxide. However, deprotection occurs under mildly acidic conditions. Thus, as a coating formulation containing a volatile base dries the volatile base evaporates and deprotection occurs. This allows for controlled room temperature crosslinking to occur with hydroxy-functionalized polymers. The present invention more specifically discloses a modified silane compound consisting of a silane having 3 or 4 acetal moieties bonded thereto.

  本发明涉及通过酸可解保护基对羟基硅烷官能团进行可逆保护。可逆保护基的开发极大地增强了硅烷的当前实用性，同时引入了进一步的新应用。例如，可逆保护的硅烷在需要室温固化和/或粘附的应用中具有特殊价值，如涂料、高分辨率成像、密封胶、粘合剂、密封剂、垫片和硅烷。可逆保护的硅烷也可以有益地用于交联剂、浸渍剂、轮胎和脱模涂层。将可逆保护的硅烷纳入涂层树脂中具有特殊价值。可逆保护的硅烷可以通过将含有可逆保护的硅烷的单体聚合到树脂中或通过后加入涂料配方中来纳入涂层树脂中。在碱性条件下（例如含有挥发性碱的涂料配方中），可逆保护的硅烷保持受保护状态。然而，在温和酸性条件下脱保护。因此，当含有挥发性碱的涂料配方干燥时，挥发性碱蒸发并发生脱保护。这允许与羟基化聚合物发生可控的室温交联。本发明更具体地揭示了一种改性硅烷化合物，其由具有3或4个缩醛基团的硅烷组成。
• OLEFIN POLYMERIZATION CATALYST, PROCESS FOR PRODUCING OLEFIN POLYMER, POLYPROPYLENE RESIN COMPOSITION AND ARTICLE COMPRISING THE SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20130109789A1

  公开（公告）日：2013-05-02

  An olefin polymerization catalyst is obtained by bringing the following components (A), (B) and (C) into contact with one another: (A) a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom and a halogen atom; (B) an organoaluminum compound; and (C) a triether represented by formula (I). An olefin polymerization solid catalyst can be provided having a sufficiently high polymerization activity and an ability to produce an olefin polymer with a low content of low-molecular weight components and amorphous components.

  一种烯烃聚合催化剂是通过将以下组分（A）、（B）和（C）彼此接触而获得的：（A）用于烯烃聚合的固体催化剂组分，其中包含钛原子、镁原子和卤素原子；（B）有机铝化合物；以及（C）由式（I）表示的三醚。可以提供具有足够高的聚合活性和能够产生低分子量成分和非晶态成分含量低的烯烃聚合物的固体聚合催化剂。
• Latex for coatings having improved flexibility
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0501272A1

  公开（公告）日：1992-09-02

  This invention relates to the synthesis of a latex which can be formulated into coatings having improved flexibility and good water resistance. Coatings of this type are particularly useful in roof coating applications because they offer excellent flexibility, excellent ultra-violet light resistance, and good water resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: (1) free radical aqueous emulsion polymerizing, at a pH of less than about 3.5, a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 30 to about 70 weight percent vinyl aromatic monomers, (b) from about 25 to about 65 weight percent of at least one alkyl acrylate monomer, (c) from about 1 to about 5 weight percent of acrylic acid, and (d) about 0.4 to about 3 weight percent methacrylic acid; in the presence of about 0.2 to 0.4 phm at least one sulfonate surfactant and in the presence of about 4 to 8 phm of at least one nonionic surface active agent having a hydrophile-lipophile balance number which is within the range of about 12 to about 20 to produce a latex; and (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.

  本发明涉及一种胶乳的合成，这种胶乳可以配制成具有更好柔韧性和良好耐水性的涂料。这种类型的涂料尤其适用于屋顶涂料应用，因为它们具有优异的柔韧性、优异的抗紫外线能力和良好的耐水性。本发明更具体地公开了一种生产中和胶乳的工艺，这种胶乳可用于制造可还原防水涂料，其工艺包括： 1： (1) 在 pH 值小于约 3.5 的条件下，对单体混合物进行自由基水乳液聚合，该单体混合物以 100 重量百分比的单体为基础包括：(a) 约 30 至约 70 重量百分比的乙烯基芳香族单体，(b) 约 25 至约 65 重量百分比的至少一种丙烯酸烷基酯单体，(c) 约 1 至约 5 重量百分比的丙烯酸，以及 (d) 约 0.4 至约 3 重量百分比的甲基丙烯酸；在约 0.2 至 0.4 phm 的至少一种磺酸盐表面活性剂和约 4 至 8 phm 的至少一种非离子表面活性剂的存在下，产生胶乳，该表面活性剂的亲水-亲脂平衡数在约 12 至约 20 的范围内；以及 (2) 用氨水将胶乳中和至 pH 值在约 7 至约 10.5 范围内，生成中和胶乳。
• Catalyst for polymerization of olefins and process for polymerization of olefins using the same
  申请人：TOHO TITANIUM CO., LTD.

  公开号：EP0665243A2

  公开（公告）日：1995-08-02

  A catalyst for the polymerization of olefins comprising (A) a solid catalyst component essentially containing magnesium, titanium, an electron donor compound, and a halogen which is prepared by contacting a magnesium compound, a titanium halide compound, and an electron donor compound, (B) an organoaluminum compound, and (C) an organosilicon compound and a process for polymerizing an olefin using the same are disclosed, the organosilicon compound (C) being represented by formula (I): wherein R1 and R2, which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms; and the cyclohexyl group and the cyclopentyl group may be substituted. Using the catalyst, a polyolefin having high stereoregularity and broad molecular weight distribution can be obtained in high yield.

  本发明公开了一种用于烯烃聚合的催化剂，该催化剂包括(A)基本上含有镁、钛、电子供体化合物和卤素的固体催化剂组分，该固体催化剂组分是通过镁化合物、卤化钛化合物和电子供体化合物接触制备的；(B)有机铝化合物；(C)有机硅化合物；以及使用该催化剂聚合烯烃的工艺，其中有机硅化合物(C)由式(I)表示： 其中 R1 和 R2 可以相同或不同，各自代表具有 1 至 3 个碳原子的烷基；环己基和环戊基可以被取代。使用该催化剂，可以高产率获得具有高立体规整度和宽分子量分布的聚烯烃。
• Aqueous coating for vinyl chloride polymer substrate
  申请人：GENCORP INC.

  公开号：EP0671448A1

  公开（公告）日：1995-09-13

  A water based coating composition provides a stain resistant layer which adheres well to a substrate and is resistant to chemical attack by common household cleaning solvents such as isopropyl alcohol. The coating composition has a very low volatile organic compound content, thus providing an environmentally desirable alternative to organic solvent based coatings. The low volatile organic compound content of the composition substantially or completely eliminates the problems and expenses associated with solvent recovery for meeting chemical emission standards, and the potential for human exposure to solvent vapor is substantially eliminated or significantly reduced. The coating composition is aqueous based and incorporates a crosslinkable acrylic polymer latex, an amino resin crosslinking agent and a crosslinking catalyst. The polymer, crosslinking agent and catalyst are dispersed and/or solubilized in an aqueous medium. The coating composition is particularly well suited for application to flexible vinyl chloride polymer substrates to produce upon curing and drying a stain resistant, easily cleanable laminate. The stain resistant laminates can be advantageously used in the manufacture of wallcoverings, luggage exteriors, upholstery, vehicle interior and seat coverings, golf bags and other sporting goods, table cloths, and other similar applications.

  一种水基涂料组合物提供了一种防污层，它能很好地附着在基材上，并能抵抗普通家用清洁溶剂（如异丙醇）的化学侵蚀。该涂料组合物的挥发性有机化合物含量极低，因此是有机溶剂型涂料的理想环保替代品。该组合物的低挥发性有机化合物含量大大消除或完全消除了与溶剂回收有关的问题和费用，以达到化学品排放标准，并且大大消除或显著降低了人类接触溶剂蒸汽的可能性。涂料组合物以水为基础，包含可交联丙烯酸聚合物胶乳、氨基树脂交联剂和交联催化剂。聚合物、交联剂和催化剂分散和/或溶解在水性介质中。这种涂料组合物特别适用于柔性氯乙烯聚合物基材，在固化和干燥后可制成抗污、易清洗的层压板。这种防污层压板可用于制造墙布、行李箱外饰、室内装潢、汽车内饰和座椅覆盖物、高尔夫球袋和其他体育用品、桌布以及其他类似用途。