[Cu(N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine)(oxalate)]*H2O | 921770-28-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine)(oxalate)]*H2O
• 英文别名: [Cu(dpdapt)(oxa)]*H2O
• CAS: 921770-28-7
• 化学式: C₂₁H₁₅CuN₇O₄*H₂O
• 分子量: 510.956
• InChiKey: VYLKFOANODWSFM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine 、 草酸铜 以 甲醇 为溶剂， 以60%的产率得到[Cu(N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine)(oxalate)]*H2O
  参考文献：
  名称：

  Three copper(II) complexes constructed from a new 1,3,5-triazine derivative ligand

  摘要：

  Three new complexes {[Cu(dpdapt)(Hhbd)] center dot 6H(2)O}(n), (1) (dpdapt = N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine, Hhbd = 2-hydroxybutanedioicate dianion), [Cu(dpdaPt)(SO4)]center dot 2H(2)O (2) and [Cu(dpdapt)(oxa)] center dot H2O (3) (oxa = oxalate dianion) have been synthesized and structurally characterized. The non-covalent interactions of pi-pi stacking and hydrogen bonding extend complexes 1-3 into supramolecular architectures, where 1 self-assembles into a ID polymeric chain by dicarboxylate bridges and exhibits a 3D framework with 1D open channels, while complexes 2 and 3 display 2D wavelike networks. Interestingly, in 1, the host framework encapsulates hexameric water clusters that are connected into ID arrays by supramolecular association along the ID open channels. The UV/vis, IR spectra, fluorescence and TG analysis for complexes 1, 2 and 3 are also discussed. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.07.012