diaquatetra(3,5-dinitrobenzoato)tetrasilver(I) | 777945-66-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diaquatetra(3,5-dinitrobenzoato)tetrasilver(I)
• 英文别名: tetrasilver;3,5-dinitrobenzoate;dihydrate
• CAS: 777945-66-1
• 化学式: C₂₈H₁₆Ag₄N₈O₂₆
• 分子量: 1311.95
• InChiKey: XSSJDYOSAZEZSW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -2.19
• 重原子数：
  66
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  529
• 氢给体数：
  2
• 氢受体数：
  26

反应信息

• 作为产物：
  描述：

  3,5-二硝基苯甲酸 、 水 、 silver(l) oxide 以 氨 为溶剂， 以83%的产率得到diaquatetra(3,5-dinitrobenzoato)tetrasilver(I)
  参考文献：
  名称：

  Synthesis and Characterization of Diaquatetra(3,5‐dinitrobenzoato)tetrasilver(I) and Polymeric (Ethylenediaminesilver(I) Di(3,5‐dinitrobenzoato)silver(I) Dihydrate)

  摘要：

  Two new silver complexes have been synthesized, diaquatetra(3,5-dinitrobenzoato)-tetrasilver(I) ( 1) and polymeric (ethylenediaminesilver(I) di(3,5-dinitrobenzoato)silver(I) dihydrate) ( 2). These two complexes were characterized by elemental analyses and X-ray crystallographic technique. The crystal structure of ( 1) belongs to the monoclinic system with the space group P2(1)/c, a = 5.685(11) angstrom, b = 16.96 angstrom, c = 19.67(4) angstrom, alpha = 90.00 degrees, beta = 90.00(3)degrees, gamma = 90.00 degrees, U = 1897(6) angstrom(3), Z = 2, Dx = 1.544 g cm(-3). The crystal structure of ( 2) belongs to the triclinic system with the space group P-1. a = 6.978(2) angstrom, beta = 12.919(5) angstrom, c = 15.0291(5) angstrom, alpha = 84.320(6)degrees, beta = 76.810(5)degrees, gamma = 79.612(6)degrees, U = 1295.2(8)(3), Z = 2, Dx = 1.882 g cm(-3).

  DOI：

  10.1081/sim-200037227