C8-Ndti | 1447814-61-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: C8-Ndti
• 英文别名: 9,19-dioctyl-3,13-dithia-9,19-diazahexacyclo[9.9.2.02,6.07,22.012,16.017,21]docosa-1,4,6,11,14,16,21-heptaene-8,10,18,20-tetrone
• CAS: 1447814-61-0
• 化学式: C₃₄H₃₈N₂O₄S₂
• 分子量: 602.819
• InChiKey: QVPXPJAAWJRDBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  42
• 可旋转键数：
  14
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  131
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,7-bis(triethylsilyl)naphtho[2,3-b:6,7-b’]dithiophene-4,5,9,10-tetracarboxylic acid diimide 在 四丁基氟化铵 、 溶剂黄146 、 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 2.5h， 生成 C8-Ndti
  参考文献：
  名称：

  N，N'-未取代的萘二噻吩二酰亚胺：通过N-烷基化和-Arylation的合成和衍生化

  摘要：

  新开发了一种高效，可扩展的合成N，N'-未取代的萘并[2,3- b：6,7 - b ']二噻吩-4,5,9,10-四羧酸二酰亚胺（NDTI）的方法，并且该化合物被用于Mitsunobu反应和与苯基硼酸的铜催化的偶联反应中，以合成一系列N-烷基和苯基取代的NDTI衍生物。NDTI衍生物的新合成方案在可大规模合成以及与广泛N的合成的相容性方面优于先前报道的NDTI衍生物-烷基和苯基衍生物，这反过来又为将NDTI衍生物广泛应用于电子材料铺平了道路。

  DOI：

  10.1021/acs.orglett.6b01785

文献信息

• Tuning the electronic properties of thiophene-annulated NDIs: the influence of the lateral fusion position
  作者：Jingjing Wen、Chengyi Xiao、Aifeng Lv、Hironobu Hayashi、Lei Zhang

  DOI：10.1039/c8cc02534g

  日期：——

  We report a new asymmetric thiophene-annulated naphthalenediimide with high electron mobilities.

  我们报告了一种具有高电子迁移率的新的对称噻吩-环戊二酰亚胺。
• Naphthodithiophenediimide (NDTI): Synthesis, Structure, and Applications
  作者：Yuta Fukutomi、Masahiro Nakano、Jian-Yong Hu、Itaru Osaka、Kazuo Takimiya

  DOI：10.1021/ja404753r

  日期：2013.8.7

  A straightforward synthesis of alpha,beta-unsubstituted and alpha-halogenated naphtho[2,3-b:6,7-b']-dithiophenediimides (NDTIs) is described. Electrochemical and optical studies of N,N-dioctyl-NDTI demonstrate that the compound has a low-lying LUMO energy level (4.0 eV below the vacuum level) and a small HOMO-LUMO gap (similar to 2.1 eV). With its interesting electronic and optical properties, in addition to its planar structure, NDTI is a promising building block for the development of novel pi-functional materials. In fact, it afforded n-channel, p-channel, and ambipolar materials, depending on the molecular modification.
• ORGANIC THIN FILM TRANSISTOR, METHOD OF MANUFACTURING ORGANIC THIN FILM TRANSISTOR, ORGANIC THIN FILM TRANSISTOR MATERIAL, ORGANIC THIN FILM TRANSISTOR COMPOSITION, ORGANIC SEMICONDUCTOR FILM, AND COMPOUND
  申请人：FUJIFILM Corporation

  公开号：US20180159043A1

  公开（公告）日：2018-06-07

  An object of the present invention is to provide an organic thin film transistor having excellent carrier mobility and excellent atmospheric stability, a novel compound, an organic thin film transistor material, an organic semiconductor film, an organic thin film transistor composition, and a method of manufacturing an organic thin film transistor using this. The organic thin film transistor according to the present invention has an organic semiconductor film containing a compound represented by Formula (1) or (2).