| 929298-49-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 929298-49-7
• 化学式: C₄₇H₇₃N₇O₈
• 分子量: 864.139
• InChiKey: GGNTZTQGOROWQH-JBQBJQEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.52
• 重原子数：
  62.0
• 可旋转键数：
  11.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  186.56
• 氢给体数：
  4.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  在 palladium on activated charcoal 作用下， 以 乙醇 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Controlling Multiple Fluorescent Signal Output in Cyclic Peptide-Based Supramolecular Systems

  摘要：

  A multicomponent equilibrium network based on self-assembling alpha,gamma-cyclic peptides with controlled fluorescence output is described. The network takes advantage of the large association constant of alpha,gamma-cyclic peptides and the controlled formation homo- and heterodimers, making use for the first time of excimer/FRET effects in conjunction for studying complex interaction networks. In addition, we study the Dapoxyl/pyrene FRET pair for the first time.

  DOI：

  10.1021/ja066885h
• 作为产物：
  描述：

  在 O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate 、 N,N-二异丙基乙胺 、 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 3.25h， 生成
  参考文献：
  名称：

  Controlling Multiple Fluorescent Signal Output in Cyclic Peptide-Based Supramolecular Systems

  摘要：

  A multicomponent equilibrium network based on self-assembling alpha,gamma-cyclic peptides with controlled fluorescence output is described. The network takes advantage of the large association constant of alpha,gamma-cyclic peptides and the controlled formation homo- and heterodimers, making use for the first time of excimer/FRET effects in conjunction for studying complex interaction networks. In addition, we study the Dapoxyl/pyrene FRET pair for the first time.

  DOI：

  10.1021/ja066885h