phenylpropanenamine | 86098-43-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenylpropanenamine
• 英文别名: phenylpropenamine；I+/--Ethylidenebenzenemethanamine；1-phenylprop-1-en-1-amine
• CAS: 86098-43-3
• 化学式: C₉H₁₁N
• 分子量: 133.193
• InChiKey: DBHSOVPFSSWHEC-UHFFFAOYSA-N

物化性质

• 沸点：
  240.2±10.0 °C(Predicted)
• 密度：
  0.969±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苯丙酮 、 六甲基二硅氮烷 在 四丁基氟化铵 作用下， 以87%的产率得到propiophenone-imine
  参考文献：
  名称：

  N-未取代酮亚胺的新型催化直接合成方法及其在一锅反应中的应用

  摘要：

  在此，我们总结了我们最近在开发合成 N-未取代酮亚胺的催化方法及其在生产各种含氮化合物的一锅反应中的应用的努力。该帐户提供了详细的背景、优化、范围和机制信息。我们希望这项工作能够促进未来对 N-未取代酮亚胺的研究。 1 简介 2 钪催化N-未取代酮亚胺的合成 3 四正丁基氟化铵催化N-未取代酮亚胺的合成 4。结论

  DOI：

  10.1055/a-2131-3448

文献信息

• MICRO/NANO MATERIALS, PRODUCTS OBTAINED BY COVALENTLY MODIFYING SURFACE OF MICRO/NANO MATERIALS WITH HYDROPHILIC MATERIALS, AND METHOD FOR MAKING SAME
  申请人：CHONGQING BOLANYING (BLY) BIOTECHNOLOGY CO., LTD.

  公开号：US20190077746A1

  公开（公告）日：2019-03-14

  Micro-nano materials, products obtained by covalently modifying the surfaces of micro/nano materials with hydrophilic materials, and methods for making the same. The micro/nano materials on the surfaces have carboxyl groups or/and pro-carboxyl groups which are converted into their active esters. The products are covalently modified by forming amide bonds between the active esters on the surfaces and the modification agents; where the modification agents are hydrophilic compounds and/or hydrophilic polymers bearing primary and/or secondary aliphatic amines. Monomers bearing carboxyl groups and/or pro-carboxyl groups are used to produce an adequate number of carboxyl groups and/or pro-carboxyl groups on the surface of a polymer material to be modified. The carboxyl groups and/or pro-carboxyl groups are converted into active esters. A reasonably-sized modification agent bearing primary and/or secondary amines, zwitterions and hydrophilic linear spacer arms is used to form amide bonds and obtain a covalently modified surface layer.

  微纳米材料，通过用亲水材料共价修饰微/纳米材料表面获得的产品，以及制备这些产品的方法。表面上的微/纳米材料具有羧基或/和前羧基，这些羧基或前羧基被转化为它们的活性酯。通过在表面上的活性酯和修饰剂之间形成酰胺键，共价修饰的产品；其中修饰剂是带有一次和/或二次脂肪胺基的亲水化合物和/或亲水性聚合物。使用带有羧基和/或前羧基的单体来产生足够数量的羧基和/或前羧基，以便在待修饰的聚合物材料表面上形成。将羧基和/或前羧基转化为活性酯。使用合理大小的带有一次和/或二次胺基、带有带电离子和亲水性线性间隔臂的修饰剂来形成酰胺键，并获得共价修饰的表面层。
• MICRO/NANOMATERIAL, PRODUCT THEREOF WITH SURFACE COVALENTLY MODIFIED WITH HYDROPHILIC MATERIAL, AND MANUFACTURING METHOD
  申请人：Chongqing Bolanying (BLY) Biotechnology Co., Ltd., China

  公开号：EP3470443A1

  公开（公告）日：2019-04-17

  Disclosed are micro-nano materials, products obtained by covalently modifying the surfaces of micro/nano materials with hydrophilic materials, and methods for making the same. The micro/nano materials on the surfaces have carboxyl groups or/and pro-carboxyl groups. The carboxyl groups or/and pro-carboxyl groups are converted into their active esters. The products are covalently modified by forming amide bonds between the active esters on the surfaces and the modification agents; where the modification agents are hydrophilic compounds and/or hydrophilic polymers bearing primary and/or secondary aliphatic amines. The method includes: using monomers bearing carboxyl groups and/or pro-carboxyl groups to generate an adequate number of carboxyl groups and/or pro-carboxyl groups on the surface of a polymer material to be modified, then converting them into active esters; using a reasonably-sized modification agent bearing primary and/or secondary amines, zwitterions and hydrophilic linear spacer arms to form amide bonds and obtain a covalently modified surface layer; regenerating active esters on the surface of a covalently modified product, then using the amide bond formation process to create multiple layers of covalent modification. High performance coating of the surface of a micro/nano material for negligible nonspecific adsorption is achieved with reasonably-sized hydrophilic modification agents.

  本发明公开了微纳米材料、通过亲水材料共价修饰微/纳米材料表面而获得的产品以及制造方法。微米/纳米材料表面具有羧基或/和原羧基。羧基或/和原羧基被转化为其活性酯。通过在表面上的活性酯和改性剂之间形成酰胺键，对产品进行共价改性；其中改性剂为亲水性化合物和/或亲水性聚合物，含有伯胺和/或仲脂族胺。该方法包括使用含有羧基和/或原羧基的单体，在待改性聚合物材料表面生成足够数量的羧基和/或原羧基，然后将其转化为活性酯；使用含有伯胺和/或仲胺、齐聚物和亲水线性间隔臂的合理大小的改性剂，形成酰胺键，获得共价改性表面层；在共价改性产品表面再生活性酯，然后使用酰胺键形成过程，形成多层共价改性层。通过合理大小的亲水改性剂，可实现微/纳米材料表面的高性能涂层，从而使非特异性吸附几乎可以忽略不计。
• Micro/nano materials, products obtained by covalently modifying surface of micro/nano materials with hydrophilic materials, and method for making same
  申请人：CHONGQING BOLANYING (BLY) BIOTECHNOLOGY CO., LTD.

  公开号：US10385013B2

  公开（公告）日：2019-08-20

  Micro-nano materials, products obtained by covalently modifying the surfaces of micro/nano materials with hydrophilic materials, and methods for making the same. The micro/nano materials on the surfaces have carboxyl groups or/and pro-carboxyl groups which are converted into their active esters. The products are covalently modified by forming amide bonds between the active esters on the surfaces and the modification agents; where the modification agents are hydrophilic compounds and/or hydrophilic polymers bearing primary and/or secondary aliphatic amines. Monomers bearing carboxyl groups and/or pro-carboxyl groups are used to produce an adequate number of carboxyl groups and/or pro-carboxyl groups on the surface of a polymer material to be modified. The carboxyl groups and/or pro-carboxyl groups are converted into active esters. A reasonably-sized modification agent bearing primary and/or secondary amines, zwitterions and hydrophilic linear spacer arms is used to form amide bonds and obtain a covalently modified surface layer.

  微纳米材料、通过亲水材料共价改性微/纳米材料表面而获得的产品以及制造方法。微米/纳米材料表面具有羧基或/和原羧基，这些羧基可转化为活性酯。通过在表面上的活性酯和改性剂之间形成酰胺键，对产品进行共价改性；其中，改性剂是亲水性化合物和/或亲水性聚合物，带有伯胺和/或仲脂族胺。含有羧基和/或原羧基的单体用于在待改性聚合物材料表面产生足够数量的羧基和/或原羧基。羧基和/或原羧基被转化为活性酯。使用含有伯胺和/或仲胺、齐聚物和亲水性线性间隔臂的合理大小的改性剂来形成酰胺键，从而获得共价改性表层。
• [EN] RAPID SYNTHESIS METHOD FOR BIOMASS-BASED AMINE COMPOUND<br/>[FR] PROCÉDÉ DE SYNTHÈSE RAPIDE D'UN COMPOSÉ AMINE À BASE DE BIOMASSE<br/>[ZH] 一种生物质基胺化物的快速合成方法
  申请人：UNIV NANJING AGRICULTURAL

  公开号：WO2020029846A1

  公开（公告）日：2020-02-13

  本发明公开了一种生物质基胺化物的快速合成方法，包括：以甲酰胺为胺源，甲酸为氢源，生物质醛酮为原料，在微波辅助加热且在无溶剂和催化剂的条件下，通过快速加热促进甲酰胺与醛酮类化合物直接加成并经甲酸还原制备得到相应的甲酰胺衍生物；甲酰胺衍生物在碱作用下经醇解选择性转化为相应一级胺化物。本发明微波辅助加热反应体系，催化效率明显高于相应的油浴体系，并且反应时间极大缩短，选择性得到显著提高，生物质醛或酮类化合物的转化率至少可达到99％，甲酰胺衍生物产率可达到85-99％；甲酰胺衍生物经醇解合成一级胺化物，产率可达92-99％。
• US4104383A
  申请人：——

  公开号：US4104383A

  公开（公告）日：1978-08-01