dimethylgallium-[4-methyl-2-(N-morpholinomethyl)-1-phenoxide] | 245525-88-6

• 英文名称: dimethylgallium-[4-methyl-2-(N-morpholinomethyl)-1-phenoxide]
• CAS: 245525-88-6
• 化学式: C₁₄H₂₂GaNO₂
• 分子量: 306.057
• InChiKey: DYFBNHDYBPEQIM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5-甲基-2-(吗啉-4-基甲基)苯酚 、 三甲基镓 以 苯 为溶剂， 以89%的产率得到dimethylgallium-[4-methyl-2-(N-morpholinomethyl)-1-phenoxide]
  参考文献：
  名称：

  Synthesis of phenols and naphthol with n-morpholinomethyl pendants and their dimethylgallium complexes: crystal structure of dimethylgallium-[4-nitro-2-(n-morpholinomethyl)-1-phenoxide]

  摘要：

  The one-pot Mannich reaction was used to synthesize 2-(n-morpholinomethyl)-1-phenol (la), 4-methyl-2-(n-morpholinomethyl)-1-phenol (Ib), 4-chloro-2-(n-morpholinomethyl)-1-phenol (Ic), 4-nitro-2-(n-morpholinomethyl)-1-phenol(ld), and 1-(n-morpholinomethyl)-naphthol (le). The dimethylgallium complexes of these compounds have been prepared, and compound 2d has been determined by X-ray crystallography. The complex 2d crystallized with one unit having two identical molecules which have intermolecular contacts between the two phenyls caused by face to face pi-pi stacking. The Ga-O bond distances are noticeably shorter than in the other dimethylgallium phenoxides reported. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00148-5