2,6-bis(3-(3,5,7,9,11,13,15-heptaisobutyl-2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1-yl)propyl)pyrrolo[3,4-f]isoindole-1,3,5,7(2H,6H)-tetraone | 1330534-02-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2,6-bis(3-(3,5,7,9,11,13,15-heptaisobutyl-2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1-yl)propyl)pyrrolo[3,4-f]isoindole-1,3,5,7(2H,6H)-tetraone
• CAS: 1330534-02-5
• 化学式: C₇₂H₁₄₀N₂O₂₈Si₁₆
• 分子量: 1931.27
• InChiKey: MMKNNXJYYJTYKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.43
• 重原子数：
  118.0
• 可旋转键数：
  36.0
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  299.66
• 氢给体数：
  0.0
• 氢受体数：
  30.0

反应信息

• 作为产物：
  描述：

  氨基丙基庚基-笼形聚倍半硅氧烷 、 均苯四甲酸二酐 在 咪唑 作用下， 反应 0.08h， 以37%的产率得到2,6-bis(3-(3,5,7,9,11,13,15-heptaisobutyl-2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1-yl)propyl)pyrrolo[3,4-f]isoindole-1,3,5,7(2H,6H)-tetraone
  参考文献：
  名称：

  Synthesis and characterization of a range of POSS imides

  摘要：

  The microwave condensation of mono-amino functionalised polyhedral oligomeric silsesquioxane (POSS) with a range of mono- and bis-anhydrides yielded the corresponding FOSS imide compounds, which were characterized by UV-Vis and fluorescence spectrophotometry. The perylene FOSS imide derivative was further characterized by single crystal X-ray crystallography. The naphthyl POSS bis/monoimide exhibited extremely weak fluorescence, whilst the perylene POSS bis-imide displayed particularly strong fluorescence, with a quantum yield approaching unity. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.05.028