[Pd2(μ-SePh)2(Me2NCH2C6H4–C,N)2] | 1040375-95-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd2(μ-SePh)2(Me2NCH2C6H4–C,N)2]
• 英文别名: [Pd₂(μ-SePh)2(Me₂NCH₂C₆H4-C,N)₂]；sym-cis-[Pd2(μ-SePh)2(N,N-dimethylbenzylamine-C,N(-H))2]
• CAS: 1040375-95-8
• 化学式: C₃₀H₃₄N₂Pd₂Se₂
• 分子量: 793.373
• InChiKey: JTMPKXXQYKLFAF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis[(benzyldimethylamino)chloropalladium(II)] 、 sodium phenylselenide 以 苯 为溶剂， 以40%的产率得到[Pd2(μ-SePh)2(Me2NCH2C6H4–C,N)2]
  参考文献：
  名称：

  Chalcogenolato-bridged cyclometallated binuclear palladium complexes: Synthesis, spectroscopy, structures of [Pd2(μ-Cl)(μ-SMes)(C10H6NMe2–C,N)2] and [Pd2(μ-SePh)2(C10H6NMe2–C,N)2]

  摘要：

  Reactions of orthometallated binuclear palladium complexes with NaER, obtained by NaBH(4) reduction of R(2)E(2) in methanol, gave complexes, [Pd(2)(mu-ER)(2)(C(boolean AND)Y)(2)] (HC(boolean AND)Y= N,N-dimethylbenzylamine (C(6)H(5)CH(2)NMe(2)), N,N-dimethylnaphthylamine (C(10)H(7)NMe(2)), tri-o-tolylphosphine {P(tol-o)(3)}; ER= SePh, SeMes, TePh, TeMes (Mes = 2,4,6-Me(3)C(6)H(2)). Similar reactions of [Pd(2)(mu-Cl)(2)(C(10)H(6)NMe(2)-C, N)(2)] with Pb(SMes)(2) or MesSH in the presence of NaHCO(3) gave chloro/thiolato-bridged complex [Pd(2)(mu-Cl)(mu-SMes)(C(10)H(6)NMe(2)-C, N)(2)]. The newly synthesized complexes were characterized by elemental analysis, UV-Vis, IR, NMR ((1)H, (13)C, (31)P, (77)Se, (125)Te) spectroscopy. These complexes crystallized out preferentially in sym-cis configuration. A low energy charge transfer transition has been identified from chalcogenolate centers to an empty pi* orbital of cyclometallated ligand in absorption spectroscopy in these complexes. The structures of [Pd(2)(mu-Cl)(mu-SMes)(C(10)H(6)NMe(2)-C, N)(2)] (1) and [Pd(2)(mu-SePh)(2)(C(10)H(6)NMe(2)-C, N)(2)] (3) have been established by single crystal X-ray diffraction analyses. In the former, the two palladium atoms are held together by chloro and thiolato bridges whereas in the latter, the two phenylselenolato ligands bridge two palladium atoms. The pyrolysis of [Pd(mu-TeMes)(C(10)H(6)NMe(2)-C, N)](2) (10) in a furnace gave Pd(7)Te(3) whereas thermolysis in TOPO afforded primarily PdTe(2). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.01.005

文献信息

• Binuclear Orthometalated N,N-Dimethylbenzylamine Complexes of Palladium(II): Synthesis, Structures and Thermal Behavior
  作者：Siddhartha Kolay、Ninad Ghavale、Amey Wadawale、Dasarathi Das、Vimal K. Jain

  DOI：10.1080/10426507.2012.757608

  日期：2013.10.1

  palladium(II) complexes of the formulae, [Pd2(μ-Epy)2(Me2NCH2C6H4-C,N)2] (2) (E = S (2a), Se (2b)), [Pd2(μ-SAr)(μ-Cl)(Me2NCH2C6H4-C,N)2] (3) (Ar = Ph (3a), Mes (Mes = 2,4,6-Me3C6H2) (3b)) and [Pd2(μ-SeAr)2(Me2NCH2C6H4-C,N)2] (4) (Ar = Ph (4a), Mes (4b)), have been synthesized by the reactions of [Pd2(μ-Cl)2(Me2NCH2C6H4-C,N)2] with lead or sodium salts of the chalcogenolate ligand. These complexes have been

  摘要 有机硫属元素桥联的环金属钯 (II) 配合物 [Pd2(μ-Epy)2(Me2NCH2C6H4-C,N)2] (2) (E = S (2a), Se (2b)), [Pd2 (μ-SAr)(μ-Cl)(Me2NCH2C6H4-C,N)2] (3) (Ar = Ph (3a), Mes (Mes = 2,4,6-Me3C6H2) (3b)) 和 [Pd2( μ-SeAr)2(Me2NCH2C6H4-C,N)2] (4) (Ar = Ph (4a), Mes (4b))，已通过 [Pd2(μ-Cl)2(Me2NCH2C6H4-C ,N)2] 与硫属元素配体的铅盐或钠盐。这些配合物已通过元素分析、质谱数据和 NMR（1H 和 77Se1H}）光谱表征。通过单晶 X 射线衍射分析确定的 2 的分子结构揭示了 Epy 桥接的头对尾排列，其中八元“(PdECN)2”环采用扭曲的扭曲船构象。2a