[Cu(N-(2-hydroxybenzyl)-glycinamide-H)2Cl2] | 908860-56-0

• 英文名称: [Cu(N-(2-hydroxybenzyl)-glycinamide-H)2Cl2]
• CAS: 908860-56-0
• 化学式: C₁₈H₂₂Cl₂Cu₂N₄O₄
• 分子量: 556.395
• InChiKey: GPCPCPLVTOIAPL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-[[(2-羟基苯基)甲基]氨基]乙酰胺 以 乙醇 、 水 为溶剂， 以57%的产率得到[Cu(N-(2-hydroxybenzyl)-glycinamide-H)2Cl2]
  参考文献：
  名称：

  Syntheses, structures and properties of copper(II) complexes containing N-(2-hydroxybenzyl)-amino amide ligands

  摘要：

  Four copper(II) complexes containing the reduced Schiff base ligands, namely, N-(2-hydroxybenzyl)-glycinamide (Hsglym) and N-(2-hydroxybenzyl)-L-alaninamide (Hsalam) have been synthesized and characterized. The crystal structures of [Cu-2(sglym)(2)Cl-2] (1), [Cu-2(salam)(2)(NO3)(2)]center dot H2O(3), [Cu-2(salam)(2)(NO3)(H2O)](NO3)center dot 1.5H(2)O (4), [Cu-2(salam)(2)](ClO4)(2)center dot 2H(2)O (5) show that the Cu(II) atoms are bridged by two phenolato oxygen atoms in the dimers. The sglym ligand bonded to Cu(II) in facial manner while salam ligand prefers to bind to Cu(II) in meridonal geometry. Variable temperature magnetic studies of 3 showed it is antiferromagnetic. These Cu(II) complexes and [Cu-2(sglym)(2)(NO3)(2)](2), exhibit very small catecholase activity as compared to the corresponding complexes containing acid functional groups. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.01.006