5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene | 1235485-13-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene
• 英文别名: 7,7-diphenyl-10-[4-(N-phenylanilino)phenyl]-3,11-dithia-7-silatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene-4-carbaldehyde
• CAS: 1235485-13-8
• 化学式: C₃₉H₂₇NOS₂Si
• 分子量: 617.867
• InChiKey: OTDVMBWXXGXLBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.12
• 重原子数：
  44
• 可旋转键数：
  7
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene 、 丙二腈 在 aluminum oxide 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以72%的产率得到5-[N,N-bis(phenylamino)phenyl]-5'-dicyanomethylidenemethyl-3,3'-diphenylsilylene-2,2'-bithiophene
  参考文献：
  名称：

  A new donor–acceptor molecule with uniaxial anisotropy for efficient vacuum-deposited organic solar cells

  摘要：

  一种新的D-A分子（TPDCDTS）采用共面二苯基取代二噻吩硅氧烷作为三苯胺（供体）和二氰乙烯（受体）的中心Β-桥，已作为小分子有机太阳能电池（SMOSC）的供体材料合成，其中C70作为受体，显示出3.82%的可观功率转换效率。

  DOI：

  10.1039/c1cc12139a
• 作为产物：
  描述：

  5-[N,N-bis(phenylamino)phenyl]-3,3'-diphenylsilylene-2,2'-bithiophene 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 以64%的产率得到5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene
  参考文献：
  名称：

  Organic Dyes Containing Coplanar Diphenyl-Substituted Dithienosilole Core for Efficient Dye-Sensitized Solar Cells

  摘要：

  Two new organic dyes adopting coplanar diphenyl-substituted dithienosilole as the central linkage have been synthesized, characterized, and used as the sensitizers for dye-sensitized solar cells (DSSCs). The best DSSC exhibited a high power conversion efficiency up to 7.6% (TP6CADTS) under AM 1.5G irradiation, reaching similar to 96% of the ruthenium dye N719-based reference cell under the same conditions.

  DOI：

  10.1021/jo100762t

文献信息

• Organic Dyes Containing Coplanar Diphenyl-Substituted Dithienosilole Core for Efficient Dye-Sensitized Solar Cells
  作者：Li-Yen Lin、Chih-Hung Tsai、Ken-Tsung Wong、Tsung-Wei Huang、Lun Hsieh、Su-Hao Liu、Hao-Wu Lin、Chung-Chih Wu、Shu-Hua Chou、Shinn-Horng Chen、An-I Tsai

  DOI：10.1021/jo100762t

  日期：2010.7.16

  Two new organic dyes adopting coplanar diphenyl-substituted dithienosilole as the central linkage have been synthesized, characterized, and used as the sensitizers for dye-sensitized solar cells (DSSCs). The best DSSC exhibited a high power conversion efficiency up to 7.6% (TP6CADTS) under AM 1.5G irradiation, reaching similar to 96% of the ruthenium dye N719-based reference cell under the same conditions.
• A new donor–acceptor molecule with uniaxial anisotropy for efficient vacuum-deposited organic solar cells
  作者：Hao-Wu Lin、Li-Yen Lin、Yi-Hong Chen、Chang-Wen Chen、Yu-Ting Lin、Shi-Wen Chiu、Ken-Tsung Wong

  DOI：10.1039/c1cc12139a

  日期：——

  A new D–π–A molecule (TPDCDTS) adopting coplanar diphenyl-substituted dithienosilole as a central π-bridge of triphenylamine (donor) and dicyanovinylene (acceptor) has been synthesized as donor material for small molecule organic solar cells (SMOSC) incorporating C70 as an acceptor showed an appreciable power conversion efficiency of 3.82%.

  一种新的D-A分子（TPDCDTS）采用共面二苯基取代二噻吩硅氧烷作为三苯胺（供体）和二氰乙烯（受体）的中心Β-桥，已作为小分子有机太阳能电池（SMOSC）的供体材料合成，其中C70作为受体，显示出3.82%的可观功率转换效率。