PdCl2(1,2-bis(dimethylphosphino)ethane) | 15559-64-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: PdCl2(1,2-bis(dimethylphosphino)ethane)
• 英文别名: [bis(dimethylphosphino)ethane]dichloropalladium；Dichloro[1,2-bis(dimethylphosphino)ethane]palladate (cento)；dichloropalladium;2-dimethylphosphanylethyl(dimethyl)phosphane
• CAS: 15559-64-5
• 化学式: C₆H₁₆Cl₂P₂Pd
• 分子量: 327.467
• InChiKey: SXMFFDGCHJXZGA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.85
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  PdCl2(1,2-bis(dimethylphosphino)ethane) 在 Cl₂ 作用下， 以 四氯化碳 为溶剂， 以>80的产率得到[1,2-bis(dimethylphosphino)ethane]tetrachloropalladium(IV)
  参考文献：
  名称：

  Gray, Leslie R.; Gulliver, David J.; Levason, William, Journal of the Chemical Society, Dalton Transactions, 1983, p. 133 - 142

  摘要：

  DOI：
• 作为产物：
  描述：

  [1,2-bis(dimethylphosphino)ethane]tetrachloropalladium(IV) 以 二氯甲烷 为溶剂， 生成 PdCl2(1,2-bis(dimethylphosphino)ethane)
  参考文献：
  名称：

  Gray, Leslie R.; Gulliver, David J.; Levason, William, Journal of the Chemical Society, Dalton Transactions, 1983, p. 133 - 142

  摘要：

  DOI：

文献信息

• Comparison of structures between platinum and palladium complexes of a tetrasilyldisilene
  作者：Hisako Hashimoto、Yumiko Sekiguchi、Yohei Sekiguchi、Takeaki Iwamoto、Chizuko Kabuto、Mistuo Kira

  DOI：10.1139/v03-108

  日期：2003.11.1

  The first η2-disilene–palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine)dichloropalladiums with a 1,2-dilithiotetrakis(trialkylsilyl)disilane, which was prepared by the reaction of a stable tetrakis(trialkylsilyl)disilene with lithium (Method A) and the direct reactions of the bis(phosphine)dichloropalladiums with the stable disilene (Method B). Comparison

  第一个 η2-二硅烯 ??钯配合物是使用两种不同的反应合成的；双（膦）二氯钯与 1,2-二硫代四（三烷基甲硅烷基）乙硅烷的反应二氯钯与稳定的二硅烯（方法 B）。二硅烯-钯配合物与相应铂配合物的X射线结构参数对比表明钯配合物是金属环，但其π-配合物特征强于铂配合物。 关键词：二硅烯配合物，钯，铂，X-射线结构，金属环，π-络合物。
• First Isolations and Structuresof the<i>cis</i>-Bis(phosphoranido) Palladium(II) and Platinum(II) Complexes
  作者：Kazumasa Kajiyama、Yoshinari Hirai、Takeshi Otsuka、Hidetaka Yuge、Takeshi Ken Miyamoto

  DOI：10.1246/cl.2000.784

  日期：2000.7

  from a P–H spirophosphorane bearing two 8-oxy-1-naphthyl groups with (dmpe)MCl2 (M; Pd, Pt) [dmpe; bis(dimethylphosphino)ethane] gives the first cis-bis(phosphoranido) palladium(II) and platinum(II) complexes. The crystal structures of the racemic isomers of the complexes are determined by the X-ray structural analyses.

  由带有两个 8-oxy-1-naphthyl 基团的 P-H 螺正膦产生的磷酰化物与 (dmpe)MCl2 (M; Pd, Pt) [dmpe; 双（二甲基膦基）乙烷]得到第一个顺式双（膦基）钯（II）和铂（II）配合物。配合物的外消旋异构体的晶体结构由 X 射线结构分析确定。
• Reactions of amides with zerovalent and divalent palladium and platinum complexes
  作者：David R. Schaad、Clark R. Landis

  DOI：10.1021/om00042a016

  日期：1992.6

  The reactions of amides (RCONH2 and CF3SO2NH2) with L2Pd(CH3)2 and L2Pt(CH3)2 and with transient L2Pt0 to yield new complexes containing palladium- and platinum-amido nitrogen bonds are reported. Photolysis of Pt(C2O4)(PEt3)2 (1) in the presence of amide generates products of the type trans-PtH-(HNR)(PEt3)2 (R = SO2CF3 (1a), COCF3 (1b)). Reaction of amides with trans-PtH-(CH3)(PEt3)2 (2), cis-PdMe2(PEt3)2 (3), cis-PtMe2(PEt3)2 (4), PdMe2(dcpe) (5), PdMe2(dmpe) (6), and PtMe2(COD) (7) produces 1a,b, trans-PdMe(HNR)(PEt3)2 (R = SO2CF3 (3a), COCF3 (3b), COCF2H (3c), COPh (3d)), PtMe(HNR)(PEt3)2 (R = SO2CF3 (4a), COCF3 (4b)), PdMe(HNR)(dcpe) (R = SO2CF3 (5a), COCF3 (5b), COPh (5c)), PdMe(HNSO2CF3)(dmpe) (6a), and PtMe(HNR)(COD) (R = SO2CF3 (7a), COCF3 (7b)), respectively. The stereochemistry and topologies of the new compounds are established by multinuclear NMR spectroscopy. The relevance of these reactions to hydroamination catalysis is discussed.