[n-BuB(CH2P-i-Pr2)3Ag(triethylphosphine)] | 1016231-36-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 磷环化合物
• 英文名称: [n-BuB(CH2P-i-Pr2)3Ag(triethylphosphine)]
• CAS: 1016231-36-9
• 化学式: C₃₁H₇₂AgBP₄
• 分子量: 687.487
• InChiKey: XASOZNJVRJOILH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.27
• 重原子数：
  37.0
• 可旋转键数：
  13.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  、 silver(I) chloride 、 三乙基膦 以 四氢呋喃 为溶剂， 以68%的产率得到[n-BuB(CH2P-i-Pr2)3Ag(triethylphosphine)]
  参考文献：
  名称：

  Tris(phosphino)borato Silver(I) Complexes as Precursors for Metallic Silver Aerosol-Assisted Chemical Vapor Deposition

  摘要：

  A series of light- and air-stable tris(phosphino)borato silver(l) complexes has been synthesized, structurally and spectroscopically characterized, and implemented in the growth of low resistivity metallic silver thin films by aerosol-assisted chemical vapor deposition (AACVD). Of the four complexes in the series, [RB(CH2PR'(2))(3)]AgPEt3 (R = Ph (1, 3), Bu-n (2, 4); R' = Ph (1, 2), Pr-i (3, 4), complexes 1 and 2 have been characterized by single-crystal X-ray diffraction. Complex 2 represents a significant improvement over previously available nonfluorinated Ag precursors, owing to ease of handling and efficient film deposition characteristics. Thermogravimetric analysis (TGA) shows that the thermolytic properties of these complexes can be significantly modified by altering the ligand structure. Polycrystalline cubic-phase Ag thin films were grown on glass, MgO(100), and 52100 steel substrates. Ag films of thicknesses 3 mu m, grown at rates of 14-18 nm/min, exhibit low levels of extraneous element contamination by X-ray photoelectron spectroscopy (XPS). Atomic force microscopy (AFM) and scanning electron microscopy (SEM) indicate that film growth proceeds primarily via an island growth (Volmer-Weber) mechanism.

  DOI：

  10.1021/ic701852x