[(p-cymene)Ru(C12H10NO2)Cl] | 252573-96-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(p-cymene)Ru(C12H10NO2)Cl]
• 英文别名: chlororuthenium(1+);2-methyl-4-oxo-1-phenylpyridin-3-olate;1-methyl-4-propan-2-ylbenzene
• CAS: 252573-96-9
• 化学式: C₂₂H₂₄ClNO₂Ru
• 分子量: 470.961
• InChiKey: MIWJUJHXMQBMFV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-hydroxy-2-methyl-1-phenyl-4-pyridinone 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 在 NaOMe 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以75%的产率得到[(p-cymene)Ru(C12H10NO2)Cl]
  参考文献：
  名称：

  Halfsandwich complexes of ruthenium(II), rhodium(III) and iridium(III) with N-substituted 3-hydroxy-2-methyl-4-pyridone ligands

  摘要：

  The synthesis and characterization of (p-cymene)Ru-II, Cp*Rh-III and Cp*Ir-III complexes with N-alkyl and N-aryl substituted 3-hydroxy-2-methyl-4-pyridone ligands is reported. All compounds display an unusually high solubility in water. With the chiral ligand N-(o-C6H4CO2Me)-3-hydroxy-2-methyl-4-pyridone two isomers were obtained but no diastereoselectivity was observed. The structure of [(p-cymene)Ru(C9H12NO2)Cl] (2) was determined by single crystal X-ray diffraction. Reactions of [p-cymene) Ru(C7H8NO2)Cl] (1) with n-butylamine and triphenylphosphine were shown to result in substitution of the chloride ligand. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00280-7