[(N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)-4-methylbutanamidato-κ2N,O)Ni(η1-CH2Ph)(PMe3)] | 1025466-81-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)-4-methylbutanamidato-κ2N,O)Ni(η1-CH2Ph)(PMe3)]
• CAS: 1025466-81-2
• 化学式: C₃₉H₅₇N₂NiOP
• 分子量: 659.558
• InChiKey: FQNLEMSUBNAXLE-WYGBOJGQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η1-CH2Ph)NiCl(PMe3)2 、 potassium N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)-4-methylbutanamidate 以 甲苯 为溶剂， 以86%的产率得到[(N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)-4-methylbutanamidato-κ2N,O)Ni(η1-CH2Ph)(PMe3)]
  参考文献：
  名称：

  Influence of Steric and Electronic Perturbations on the Polymerization Activities of α-Iminocarboxamide Nickel Complexes

  摘要：

  A series of N,O-bound, neutral nickel complexes containing alpha-iminocarboxamide, eta(1)-CH2Ph, and PMe3 ligands were synthesized to examine the effect of steric and electronic variations at the site adjacent to the imine functionality. These complexes were subsequently activated with Ni(COD)(2) for use in ethylene homopolymerization and ethylene/norbornene acetate (NBA) copolymerization reactions. As the bulk of the substituents is increased, one observes a progressive decrease in the rate of ring rotation, a more crowded coordination sphere around nickel, increased monomer consumption activity, and higher molecular weights of the products. Copolymerization reactions showed that the increased crowding around nickel decreases the reactivity of NBA relative to ethylene. As electron density is removed from the metal center, the catalytic species become more active toward ethylene and are more prone to interact with the functionality on NBA.

  DOI：

  10.1021/om8000263