| 892500-67-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 892500-67-3
• 化学式: C₅₈H₄₅BF₉NP₃Rh
• 分子量: 1134.62
• InChiKey: HKKXWNRPBJHJMR-OEIUOOMRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium cyanotris(trifluoromethyl)borate 、 Wilkinson's catalyst 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  (PPh₃)₃RhCNB(CF₃)₃ and (PPh₃)₃RhNCB(CF₃)₃:  Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphine)rhodium(I)

  摘要：

  The reactions of K[(CF3)(3)BNC] and K[(CF3)(3)BCN] with (PPh3)(3)RhCl in ethanol resulted in the rhodium(I) complexes (PPh3)(3)RhNCB(CF3)(3) and (PPh3)(3)RhCNB(CF3)(3), respectively. Their N-15-labeled isotopomers were synthesized from the corresponding borate anions. The complexes were characterized by UV, Raman, and multi-NMR spectroscopy, and the crystal structures were obtained. The spectroscopic and structural data are compared to those of the potassium borates and to related rhodium(I) complexes.

  DOI：

  10.1021/om060135z