3-N,3-N,11-N,11-N-tetramethyl-2,4,10,12-tetraoxa-3,11-diphosphatricyclo[11.3.1.15,9]octadeca-1(17),5(18),6,8,13,15-hexaene-3,11-diamine | 244217-60-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-N,3-N,11-N,11-N-tetramethyl-2,4,10,12-tetraoxa-3,11-diphosphatricyclo[11.3.1.15,9]octadeca-1(17),5(18),6,8,13,15-hexaene-3,11-diamine
• CAS: 244217-60-5
• 化学式: C₁₆H₂₀N₂O₄P₂
• 分子量: 366.293
• InChiKey: CNYSSHDWXJEOPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  59
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  叠氮苯 、 3-N,3-N,11-N,11-N-tetramethyl-2,4,10,12-tetraoxa-3,11-diphosphatricyclo[11.3.1.15,9]octadeca-1(17),5(18),6,8,13,15-hexaene-3,11-diamine 以 苯 为溶剂， 以23%的产率得到cyclo[bis[m-phenylene(dimethylamido)(phenylimido)phosphate]]
  参考文献：
  名称：

  Yankovich; Rasadkina; Nifant'ev, Russian Journal of General Chemistry, 1999, vol. 69, # 7, p. 1182 - 1183

  摘要：

  DOI：
• 作为产物：
  描述：

  3-[bis(dimethylamino)phosphanyloxy]phenol 以 1,4-二氧六环 为溶剂， 生成 3-N,3-N,11-N,11-N-tetramethyl-2,4,10,12-tetraoxa-3,11-diphosphatricyclo[11.3.1.15,9]octadeca-1(17),5(18),6,8,13,15-hexaene-3,11-diamine
  参考文献：
  名称：

  摘要：

  Reaction of resorcinol with phosphorous triamides containing various aliphatic radicals was studied. The preferential cleavage from phosphorus of the diisopropylamino group compared with the less bulky dimethylamino group was observed for the first time. It was shown that resorcinol is easily phosphorylated under mild conditions independent of the nature of substituent on nitrogen, but sterically hindered bulky radicals on nitrogen slow down phenolysis not only of the first, but also of the second amido group.

  DOI：

  10.1023/a:1020807208325

文献信息

• Nifant'ev, E. E.; Rasadkina, E. N.; Yankovich, I. V., Russian Journal of General Chemistry, 1999, vol. 69, # 1, p. 32 - 38
  作者：Nifant'ev, E. E.、Rasadkina, E. N.、Yankovich, I. V.、Vasyanina, L. K.、Bel'skii, V. K.、Stash, A. I.

  DOI：——

  日期：——