dichloro(N-difluorophosphino-N'-trimethylsilyl-carbodiimide)2 platinum(II) | 142954-19-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: dichloro(N-difluorophosphino-N'-trimethylsilyl-carbodiimide)2 platinum(II)
• CAS: 142954-19-6
• 化学式: C₈H₁₈Cl₂F₄N₄P₂PtSi₂
• 分子量: 630.356
• InChiKey: RAMJMMBCXXRNRZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  23.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  49.44
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 N-trimethylsilylcarbodiimido-N'-difluorophosphine 以 二氯甲烷 为溶剂， 生成 dichloro(N-difluorophosphino-N'-trimethylsilyl-carbodiimide)2 platinum(II)
  参考文献：
  名称：

  Preparation, structure and electrical conduction properties of polymeric coordination compounds of carbodiimide-PIIIF ligands

  摘要：

  In the reaction of bis(trimethylsilyl)carbodiimide (1) with excess PF2Cl only the monosubstituted carbodiimide 2a was obtained. The carbodiimide structure is suggested by N-15 and Si-29 NMR spectra. Two equivalents of 2a were found to react with (COD)PtCl2 (3) (COD = 1,5-cyclooctadiene) with the displacement of COD and the formation of 4, which underwent rapid loss of trimethylchlorosilane forming the trimer 5 and the polymer 6, which was an insulator. When 6 was doped with SbF5, TTF (tetrathiafulvalene), [(C4H9)4N]+[BF4]-, [NO]+[BF4]- or [(C4H9)4N]+[PF6]-, its electrical conductivity increased by about 13 orders of magnitude.

  DOI：

  10.1016/s0277-5387(00)84480-0