| 139941-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 139941-53-0
• 化学式: C₃₂H₂₆CoN₆
• 分子量: 553.592
• InChiKey: BGNIFGVKYQBRNS-BNLRVGSJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 N-pyrrol-2-ylmethylene-aniline 、 钴 在 tetraethylammonium perchlorate 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical synthesis of cobalt(II) and cobalt(III) complexes of Schiff bases: The crystal structure of tris{2-[(2-methylphenyl)iminomethyl] pyrrolato}cobalt(III)

  摘要：

  The electrochemical oxidation of anodic cobalt in an acetonitrile solution of Schiff bases (HL) derived from H-pyrrole-2-carbaldehyde and substituted anilines gives solutions from which [CoL3] complexes were obtained. When 1,10-phenanthroline (phen) or 2,2'-bipyridine (bipy) was added to the electrolytic phase, [CoL2 phen] or [CoL2 bipy] are obtained. The crystal structure of tris{2-[(2-methylphenyl)iminomethyl]pyrrolato} cobalt(III) has been determined by X-ray diffraction. The crystal structure consists of monomeric molecules in which the central CoN6 unit has a slightly distorted octahedral geometry. The electronic, IR and H-1 NMR spectra of the complexes are discussed and related to the structure.

  DOI：

  10.1016/s0277-5387(00)83287-8