N-(4-((2-((2,6-diisopropylphenyl)amino)ethyl)imino)pent-2-en-2-yl)-2,6-diisopropylaniline | 1139849-93-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4-((2-((2,6-diisopropylphenyl)amino)ethyl)imino)pent-2-en-2-yl)-2,6-diisopropylaniline
• CAS: 1139849-93-6
• 化学式: C₃₁H₄₇N₃
• 分子量: 461.734
• InChiKey: NJCVDQQYKLNCMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.07
• 重原子数：
  34.0
• 可旋转键数：
  11.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  36.42
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III) 、 N-(4-((2-((2,6-diisopropylphenyl)amino)ethyl)imino)pent-2-en-2-yl)-2,6-diisopropylaniline 以 正己烷 为溶剂， 以59%的产率得到
  参考文献：
  名称：

  Monoalkyllanthanide Complexes with New β-Diketiminato Derivative Dianionic Ligands

  摘要：

  A new class of beta-diketiminato derivative dianionic ligands was designed, and three ligand precursors [CH3C(ArNH)CHC(CH3)(NCH2CH2-NHR)] (Ar = 2,6-(Pr-i)(2)C6H3; R = Bu-t (H2M), 2,6-(CH3)(2)C6H3 (H(2)L2), 2,6-(Pr-i)(2)C6H3 (H(2)L3)) were synthesized. The alkane elimination reactions between these ligand precursors and Ln(CH2SiMe3)(3)(THF)(n) provided eight five-coordinate monoalkyllanthanide complexes, in which the ligand serves as a tridentate dianionic donor, with one -CH2SiMe3 and one THF molecule completing the five-coordinate center. These monoalkyl complexes exhibited low to very high catalytic activities for intramolecular hydroamination of 2,2-dimethyl-1-aminopent-4-ene. The catalytic activity increased with increasing metal ion size. For the Nd complex, 98% yield was obtained in 1 h at 60 degrees C with 0.5 mol % catalyst loading.

  DOI：

  10.1021/om900040r