3-iodo-o-terphenyl | 343227-09-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-iodo-o-terphenyl
• 英文别名: 1-Iodo-3-(2-phenylphenyl)benzene
• CAS: 343227-09-8
• 化学式: C₁₈H₁₃I
• 分子量: 356.206
• InChiKey: YARCBQCWJAVZTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-iodo-o-terphenyl 以60%的产率得到
  参考文献：
  名称：

  IBUKI EHCHI; OZASA SHIGERU; EUJIOKA YASUHIRO; KITAMURA HIROHIKO, CHEM. AND PHARM. BULL., 1980, 28, NO 5, 1468-1476

  摘要：

  DOI：
• 作为产物：
  描述：

  3-amino-o-terphenyl hydrochloride 在 硫酸 、 potassium iodide 、 sodium nitrite 作用下， 生成 3-iodo-o-terphenyl
  参考文献：
  名称：

  Ibuki, Eiichi; Ozasa, Shigeru; Fujioka, Yasuhiro, Chemical and pharmaceutical bulletin, 1980, vol. 28, # 5, p. 1468 - 1476

  摘要：

  DOI：

文献信息

• Polyphenyl synthesis by means of the Kharash-type Grignard cross-coupling reaction.
  作者：EIICHI IBUKI、SHIGERU OZASA、YASUHIRO FUJIOKA、MOTOFUMI OKADA、YOSHIHIKO YANAGIHARA

  DOI：10.1248/cpb.30.2369

  日期：——

  A series of twenty-seven polyphenyls, including quater-to sexiphenyls, was synthesized by the cross-coupling reaction of aryl Grignard reagents with arylene diiodides in the presence of bis (acetylacetonato) nickel (II). Twenty of them were obtained in fairly good yields (50-95%) under mild conditions at temperatures below ca. 60°C in ether-benzene solution within a few hours. In the cases of the remaining seven polyphenyls, however, lower yields (1-34%) were inevitable owing to the sterically crowded geometry of the reactant (s). Thus, the Kharash-type Grignard cross-coupling reaction was proved to be an efficient and convenient method for synthesizing a variety of polyphenyls, except in the cases of reactants with remarkably crowded geometry. The infrared, ultraviolet, and proton magnetic resonance spectral properties of several polyphenyls including three new compounds, 3-(2-biphenylyl)-o-quaterphenyl, 6'-(3-biphenylyl)-m-quaterphenyl, and 3, 4'-di (2-biphenylyl) biphenyl, are presented and discussed.

  合成了一系列二十七种多酚类化合物，包括四苯到六苯，通过芳基格氏试剂与芳烃二碘化物在双（乙酰丙酮）镍（II）的存在下进行交叉偶联反应。在温度低于约60°C的醚-苯溶液中，在温和条件下，这二十种化合物的产率相当不错（50-95%），反应时间为几小时。然而，在另外七种多酚类化合物的情况下，由于反应物的立体拥挤几何结构，不可避免地产率较低（1-34%）。因此，Kharash型格氏交叉偶联反应被证明是一种高效且便利的方法用于合成各种多酚类化合物，但在具有显著拥挤几何形状的反应物情况下例外。文中介绍并讨论了包括三个新化合物（3-(2-联苯基)-o-四苯、6'-(3-联苯基)-m-四苯、和3,4'-二（2-联苯基）联苯）在内的几种多酚类化合物的红外、紫外及质子磁共振光谱特性。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170346025A1

  公开（公告）日：2017-11-30

  An organic light-emitting device including a first electrode, a second electrode facing the first electrode, and an organic layer disposed between the first electrode and the second electrode, wherein the organic layer includes an emission layer, wherein the organic layer further includes i) an organometallic compound represented by Formula 1, and ii) at least one selected from a first compound represented by Formula 51, a second compound represented by Formula 61, a third compound represented by Formula 81, and a fourth compound represented by Formula 91, wherein Formulae 1, 51, 61, 81, and 91 are the same as described in the specification.

  一种有机发光器件，包括第一电极、面向第一电极的第二电极和设置在第一电极和第二电极之间的有机层，其中有机层包括发射层，有机层还包括i) 由式1表示的有机金属化合物，和ii) 至少选自由式51表示的第一化合物、由式61表示的第二化合物、由式81表示的第三化合物和由式91表示的第四化合物中的一种，其中式1、51、61、81和91如规范中描述的一样。
• ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY APPARATUS
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20170331067A1

  公开（公告）日：2017-11-16

  The present invention relates to an organic optoelectronic device and a display apparatus comprising same, the organic optoelectronic device comprising: an anode and a cathode facing each other; a light-emitting layer located between the anode and cathode; a hole transport layer located between the anode and light-emitting layer; an auxiliary hole transport layer located between the hole transport layer and light-emitting layer; an electron transport layer located between the cathode and light-emitting layer; and an auxiliary electron transport layer between the electron transport layer and light-emitting layer, wherein the auxiliary electron transport layer comprises at least one type of a first compound expressed by a particular Chemical Formula, and the auxiliary hole transport layer comprises at least one type of a second compound expressed by a particular Chemical Formula.

  本发明涉及一种有机光电器件和包括该器件的显示装置，所述有机光电器件包括：面对彼此的阳极和阴极；位于阳极和阴极之间的发光层；位于阳极和发光层之间的空穴传输层；位于空穴传输层和发光层之间的辅助空穴传输层；位于阴极和发光层之间的电子传输层；以及位于电子传输层和发光层之间的辅助电子传输层，其中辅助电子传输层包括至少一种由特定化学式表示的第一化合物，而辅助空穴传输层包括至少一种由特定化学式表示的第二化合物。
• IBUKI, EIICHI;OZASA, SHIGERU;FUJIOKA, YASUHIRO;OKADA, MOTOFUMI;YANAGIHARA+, CHEM. AND PHARM. BULL., 1982, 30, N 7, 2369-2379
  作者：IBUKI, EIICHI、OZASA, SHIGERU、FUJIOKA, YASUHIRO、OKADA, MOTOFUMI、YANAGIHARA+

  DOI：——

  日期：——
• COMPOSITION FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20190214573A1

  公开（公告）日：2019-07-11

  The present invention relates to a composition for an organic optoelectronic device, the composition comprising: a first host compound represented by Chemical Formula 1 below; and a second host compound represented by Chemical Formula 2 below, to an organic optoelectronic device using the composition and a display device. The details of Chemical Formulas 1 and 2 above are as defined in the specification.