[Cu(acetylacetonato)(1,6-bis(2-thiophene)-2,5-diazahexane)]ClO4 | 872441-97-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu(acetylacetonato)(1,6-bis(2-thiophene)-2,5-diazahexane)]ClO4
• 英文别名: [Cu(acac)(enTph)]ClO4
• CAS: 872441-97-9
• 化学式: C₅H₇O₂*C₁₂H₁₆N₂S₂*ClO₄*Cu
• 分子量: 514.51
• InChiKey: AHQPTMMXFMVTCR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 1,6-bis(2-thiophenyl)-2,5-diazahexane 、 乙酰丙酮 在 Na₂CO₃ 作用下， 以 乙醇 、 水 为溶剂， 以76%的产率得到[Cu(acetylacetonato)(1,6-bis(2-thiophene)-2,5-diazahexane)]ClO4
  参考文献：
  名称：

  Synthesis, structural and solvent influence studies on solvatochromic of acetylacetonatocopper(II) with N,N′-dibenzylic or thiophene derivatives of ethylenediamine complexes

  摘要：

  Five mixed-chelate copper(II) complexes with the general formula [Cu(acac)(diam)]ClO4, where acac is acetylacetonate ion and diam is N,N'-dibenzylic or thiophene derivatives of ethylenediamine were prepared and characterized by elemental analysis, spectroscopic and conductance measurements. The X-ray crystal analysis of these complexes demonstrated that ClO4- ions are bound weakly above and below of the chelate plane. In solution, the perchlorate ions are driven out by solvent molecules leading to their solvatochromism. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.07.018