| 206880-60-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 206880-60-6
• 化学式: C₁₆H₂₄Cl₂N₂O₄P₂Pt
• 分子量: 636.311
• InChiKey: LJIZFMWWKIFPGB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 3-(Dimethyl-phosphinoylmethoxy)-pyridine 以 乙腈 为溶剂， 以34%的产率得到
  参考文献：
  名称：

  Novel platinum (II) complexes with (pyridyloxymethylene)dimethylphosphine oxides-synthesis, IR and Raman study.

  摘要：

  The synthesis and spectroscopic properties of novel platinum (II) halide complexes with (4-pyridyloxymethylene)dimethylphosphine oxide (p-tpo) and (3-pyridyloxymethylene)dimethylphosphine oxide (m-tpo) are reported. The vibrational (IR and Raman) and physical data are in agreement with suggested stoicheiometry ML2Cl2 (L = p-tpo and m-tpo) and cis-square planar PtN2Cl2 configuration. Both p-tpo and m-tpo act as monodentate ligands and coordinate through the pyridyloxymethylene ring nitrogen to the metal ion. IR and Raman spectra exhibit no shift to lower frequencies of the nu(P=O) and thus provide unambiguous evidence for a free P=O oxygen. Normal coordinate analysis (NCA) calculations of both ligands confirm the monodentate coordination of the ligands. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(97)00260-6