1,8,15,22-tetranitrophthalocyanatozinc (II) | 135516-60-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,8,15,22-tetranitrophthalocyanatozinc (II)
• 英文别名: Zn(II) 1,8,15,22-tetranitrophthalocyanine；zinc tetra-3-nitrophthalocyanine；zinc(II) 3,3',3'',3'''-tetranitro phthalocyanine；1,8,15,22-tetranitro zinc(II) phthalocyanine；zinc(II)-18,24,30,36-tetranitro-phthalocyanine；3,3',3'',3'''-tetranitro zinc phthalocyanine；Zinc(II) 1,8,15,22-tetra(nitro)phthalocyanine；zinc;5,14,23,32-tetranitro-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene
• CAS: 135516-60-8
• 化学式: C₃₂H₁₂N₁₂O₈Zn
• 分子量: 757.913
• InChiKey: SQJUUUPZOAGCTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.76
• 重原子数：
  53
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  259
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,8,15,22-tetranitrophthalocyanatozinc (II) 在 吡啶 、 吡啶盐酸盐 作用下， 反应 17.0h， 以87.2%的产率得到tetra-3-nitrophthalocyanine
  参考文献：
  名称：

  [EN] PREPARATION AND USES OF GUANIDINIUM-MODIFIED PORPHYRINS AND PHTHALOCYANINES
  [FR] PRÉPARATION ET UTILISATIONS DE PORPHYRINES ET PHTALOCYANINES MODIFIÉES PAR LA GUANIDINE

  摘要：

  公开号：

  WO2010028780A3
• 作为产物：
  描述：

  3-硝基邻苯二甲酸酐 以22%的产率得到
  参考文献：
  名称：

  NEGRIMOVSKIJ, V. M.;DERKACHEVA, V. M.;KALIYA, O. L.;LUKYANETS, E. A., ZH. OBSHCH. XIMII, 61,(1991) N, S. 460-470

  摘要：

  DOI：

文献信息

• Novel catalyst of zinc tetraamino-phthalocyanine supported by multi-walled carbon nanotubes with enhanced visible-light photocatalytic activity
  作者：Yi Wan、Qian Liang、Tiantian Cong、Xinyu Wang、Yuyao Tao、Manyou Sun、Zhongyu Li、Song Xu

  DOI：10.1039/c5ra10462a

  日期：——

  Zinc tetraamino-phthalocyanine (ZnTAPc) supported by multi-walled carbon nanotubes (MWCNTs) hybrid materials were successfully fabricated by the method of chemical grafting and their photocatalysis behavior was reported.

  采用化学嫁接方法成功制备了由多壁碳纳米管（MWCNTs）支持的四氨基酞菁锌（ZNTa href=https://www.molaid.com/MS_164855 target="_blank">TAPc）杂化材料，并报道了它们的光催化行为。
• Negrimovskii, V. M.; Derkacheva, V. M.; Kaliya, O. L., Journal of general chemistry of the USSR, 1991, vol. 61, p. 419 - 428
  作者：Negrimovskii, V. M.、Derkacheva, V. M.、Kaliya, O. L.、Luk'yanets, E. A.

  DOI：——

  日期：——
• Synthesis, Magnetic, Spectral and Therhal Studies on Iietal(II) 1,8,15,224 Tetrantrophthalocyanines
  作者：M. P. Somashekarappa、J. Keshavayya

  DOI：10.1080/00945719909349486

  日期：1999.5
• Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes
  作者：M. H. Moinuddin khan、Fasiulla、J. Keshavayya、K. R. Venugopala Reddy

  DOI：10.1134/s0036023608010117

  日期：2008.1

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.
• Synthesis and characterization of three covalently linked porphyrin-phthalocyanine pentamers with nucleophilic substitution
  作者：Samira Osati、Nasser Safari、Parisa Rajabali Jamaat

  DOI：10.1016/j.ica.2010.03.022

  日期：2010.6

  In this paper the synthetic methods of three covalently linked porphyrin-phthalocyanine heteropentamers, containing four units of porphyrin linked to a central phthalocyanine (Mpor-LPc; M = 2H, Fe, L = Zn, Fe), are described. The synthetic strategy is on the basis of nucleophilic substitution reactions between [1,8,15,22-tetra nitro phthalocyanines] and [5-(4-hydroxy phenyl)-10,15,20-triphenyl porphyrins] as the phenolic alcohols. Porphyrins are linked with oxygen as spacer through meso position of phenyl group to phthalocyanines. These macromolecules were characterized by H-1 NMR, UV-Vis, IR, fluorescence and mass spectroscopy. The electronic absorption spectrums of the hetero-dyad systems changed significantly upon coupling and showed a great red shift in the phthalocyanine Q-bands. These changes confirm the electron-donating effects of the porphyrin units and the extension of conjugated pi-systems. The emission spectra of the products supports intramolecular energy and charge transfer between the sub-units. (C) 2010 Elsevier B.V. All rights reserved.