[Ag(ClO4)(1,3-bis(diphenylphosphino)propane)]2 C54H52Ag2Cl2O8P4, α | 844842-25-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag(ClO4)(1,3-bis(diphenylphosphino)propane)]2 C54H52Ag2Cl2O8P4, α
• 英文别名: [Ag(ClO4)(dppp)]2；[Ag(ClO4)(1,3-bis(diphenylphosphino)propane)]2
• CAS: 844842-25-7；844842-75-7
• 化学式: C₅₄H₅₂Ag₂Cl₂O₈P₄
• 分子量: 1239.54
• InChiKey: GXRMMHAAISEVAO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,3-双(二苯基膦)丙烷 、 silver perchlorate 以 乙醇 为溶剂， 以64%的产率得到[Ag(ClO4)(1,3-bis(diphenylphosphino)propane)]2 C54H52Ag2Cl2O8P4, α
  参考文献：
  名称：

  The structural definition of adducts of stoichiometry MX:dppx (1:1) M=CuI, AgI, X=simple anion, dppx=Ph2P(CH2)xPPh2, x=3–6

  摘要：

  Single crystal X-ray structural characterizations are recorded for a wide range of adducts of the form MX:dppx (1:1)((n)), M = silver(I) (predominantly), copper(I), X = simple (pseudo-) halide or oxy-anion (the latter spanning, where accessible, perchlorate, nitrate, carboxylate - a range of increasing basicity), dppx=bis(diphenylphosphino)alkane, Ph2P(CH2)(x)PPh2, x = 3-6. Adducts are defined of two binuclear forms: (i) [LM(mu-X)(2)L], with each ligand chelating a single metal atom, and (ii) [M(mu-X)(2)(mu-(P-L-P'))(2)M'] where both ligands L and halides bridge the two metal atoms; a few adducts Lire defined as polymers, the ligands connecting M(p-X)2M' kernels, this motif persisting in all forms. Synthetic procedures for all adducts have been reported. All compounds have been characterized both in solution (H-1, C-13, P-31 NMR, ESI MS) and in the solid state (IR). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.047