2,3-dihydro-1,4-benzodioxine-5,8-diyldimethyl diacetate | 1004312-08-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二恶烷
• 英文名称: 2,3-dihydro-1,4-benzodioxine-5,8-diyldimethyl diacetate
• 英文别名: 2,3-Di-hydro-1,4-benzodioxine-5,8-diyldimethyl diacetate；[5-(acetyloxymethyl)-2,3-dihydro-1,4-benzodioxin-8-yl]methyl acetate
• CAS: 1004312-08-6
• 化学式: C₁₄H₁₆O₆
• 分子量: 280.277
• InChiKey: JTSNXDCXWWGLKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3-dihydro-1,4-benzodioxine-5,8-diyldimethyl diacetate 在 氯化亚砜 、 水 、 potassium carbonate 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 为溶剂， 反应 51.5h， 生成 5,8-bis(chloromethyl)-2,3-dihydro-1,4-benzodioxine
  参考文献：
  名称：

  Bis(1,3-dithiole-2-chalcogenones) and tetrathiafulvalenes in the synthesis of bridged tetrathiafulvalene-containing structures

  摘要：

  Bis(1,3-dithiole-2-chalcogenones) in which the 1,3-dithiole fragments are linked through various bridging groups were synthesized by different methods. Some of these compounds were converted into substituted tetrathiafulvalenes with bridged 1,3-dithiole rings. The same structures were synthesized from preliminarily prepared symmetric tetrathiafulvalenes containing 2-cyanoethylsulfanyl groups in both 1,3-dithiole rings. Similar spacers were used to bridge two tetrathiafulvalene fragments. Syntheses of the involved initial compounds were described.

  DOI：

  10.1134/s1070428007010186
• 作为产物：
  描述：

  5,8-bis(morpholinomethyl)-2,3-dihydro-1,4-benzodioxin 、 乙酸酐 在 sodium acetate 作用下， 反应 60.0h， 生成 2,3-dihydro-1,4-benzodioxine-5,8-diyldimethyl diacetate
  参考文献：
  名称：

  Bis(1,3-dithiole-2-chalcogenones) and tetrathiafulvalenes in the synthesis of bridged tetrathiafulvalene-containing structures

  摘要：

  Bis(1,3-dithiole-2-chalcogenones) in which the 1,3-dithiole fragments are linked through various bridging groups were synthesized by different methods. Some of these compounds were converted into substituted tetrathiafulvalenes with bridged 1,3-dithiole rings. The same structures were synthesized from preliminarily prepared symmetric tetrathiafulvalenes containing 2-cyanoethylsulfanyl groups in both 1,3-dithiole rings. Similar spacers were used to bridge two tetrathiafulvalene fragments. Syntheses of the involved initial compounds were described.

  DOI：

  10.1134/s1070428007010186