bis[2-(N,N-dimethylamino)methylferrocene] (trihydrido)aluminum | 201422-83-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis[2-(N,N-dimethylamino)methylferrocene] (trihydrido)aluminum
• 英文别名: alumane;cyclopenta-1,3-diene;1-cyclopenta-1,3-dien-1-yl-N,N-dimethylmethanamine;iron(2+)
• CAS: 201422-83-5
• 化学式: C₂₆H₃₇AlFe₂N₂
• 分子量: 516.269
• InChiKey: QGJCZTWTRAVVDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trimethylamine alane 、 N,N-dimethylaminomethylferrocene 以 正戊烷 为溶剂， 以92%的产率得到bis[2-(N,N-dimethylamino)methylferrocene] (trihydrido)aluminum
  参考文献：
  名称：

  Coordination of alane and aluminum alkyls to the N-donor atom of side chain functionalized cyclopentadienyl iron and nickel complexes; structure of {[(C5H5)(C5H4CH2NMe2)]Fe}2AlH3

  摘要：

  The synthesis of iron and nickel complexes with interaction of alane and trialkylaluminum compounds to the amino group is described. Treatment of [2-(N,N-dimethylamino)methyl] ferrocene [(C5H5)(C5H4CH2NMe2)] Fe (1) with trimethylaminealane (H-3-Al-NMe3), leads to the formation of the iron alane complex {[(C5H5)(C5H4CH2NMe2)]Fe}(2)AlH3 (2), with a five-coordinated aluminum center. The structure of 2 has been determined by single-crystal X-ray diffraction. The reaction of FeCl2 with two equivalents of {(C5H4CH2CH2NMe2)Li} leads to the formation of [(C5H4CH2CH2NMe2)(2)Fe] (3). Complex 3 reacts quantitatively with two equivalents of trimethylaluminum to the compound [(C5H4CH2CH2NMe2)(2)Fe](AlMe3)(2) (4). Addition of trimethylaluminum or triethylaluminum to the nickel complex [(C5H4CH2CH2NMe2)(2)Ni]Ni (5) give the paramagnetic nickel aluminum compounds [(C5H4CH2CH2NMe2)(2)Ni](AlMe3)(2) (6a) and [(C5H4CH2CH2NMe2)(2)Ni](AlEt3)(2) (6b), respectively. These compounds were characterized by H-1, C-13 and Al-27 NMR, elemental analysis and mass spectroscopy. Studies to deposit intermetallic thin films using these compounds as bimetallic single source precursors revealed that aluminum was deposited, only. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00359-8