[Pd(η3-1-Ph-C3H4)(FcCH=N-(C6H4-2-SMe))][PF6]*H2O | 924888-09-5

• 英文名称: [Pd(η3-1-Ph-C3H4)(FcCH=N-(C6H4-2-SMe))][PF6]*H2O
• CAS: 924888-09-5
• 化学式: C₂₇H₂₆FeNPdS*F₆P*H₂O
• 分子量: 721.823
• InChiKey: DAKYYNKIIFEDKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)] 、 cyclopenta-1,3-diene;1-cyclopenta-2,4-dien-1-yl-N-(2-methylsulfanylphenyl)methanimine;iron(2+) 以 丙酮 为溶剂， 以82%的产率得到[Pd(η3-1-Ph-C3H4)(FcCH=N-(C6H4-2-SMe))][PF6]*H2O
  参考文献：
  名称：

  Heterodimetallic Palladium(II) Complexes with Bidentate (N,S) or Terdentate (C,N,S)^- Ferrocenyl Ligands. The Effect of the Ligand Donor Atoms on the Regioselectivity of the Allylic Alkylation of Cinnamyl Acetate

  摘要：

  The synthesis and characterization of [Pd(eta(3)-1-R-1-C3H4){FcCHN-(C6H4-2SMe)}][PF6] {R-1 = H (2a) or Ph (3a)} are described. A comparative study of the catalytic activity of (a) the mixtures containing [Pd(eta(3)-C3H5)(mu-Cl)](2) and its parent ligand (1a) or H2N-C6H4-2SMe (4) and (b) the palladacycles [Pd{[(eta(5)-C5H3)-CHN-(C6H4-2SMe)]Fe(eta(5)-C5H5)}Cl] (5a), [Pd{(2-CH2-4,6-Me2C6H2)-CHN-(C6H4-2SMe)}Cl] (5b) in the allylic alkylation of (E)-3-phenyl-2-propenyl (cinnamyl) acetate with sodium diethyl 2-methylmalonate is also reported.

  DOI：

  10.1021/om060647d