| 859169-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 859169-82-7
• 化学式: C₃₆H₄₈N₂O₂Pd
• 分子量: 648.198
• InChiKey: JWXRJSOAALDGRE-LBXJRBGQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-二甲氨基苄叔丁胺 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Neutral N−O Chelated Palladium(II) Complexes:  Syntheses, Characterization, and Reactivity

  摘要：

  A series of neutral salicylaldiminato MID complexes, Pd(Me)(Ph-CH=N-R')[3-Bu-t-2-(O)C6H3-CH=N-2,6-di-Pr-i-C6H3] (R = CH3, n-Pr, tert-Bu, Ph, benzyl) (3a-3e) and Pd(Me)[2(CH=N-t-Bu)-Py][3-Bu-t-2-(O)C6H3-CH=N-2,6-di-Pr-i-C6H: I (4), have been synthesized and characterized. The structures of complexes 3a, 3c-3e, and 4 have been confirmed by X-ray analysis. NMR studies utilizing 3c indicate that the insertion of CO into the Pd-Me bond occurs through a five-coordinate intermediate. The acyl compounds in turn undergo imine insertion. The neutral complexes 3a-3e show moderate catalytic activity for the polymerization of methyl acrylate at ambient temperature. However, a radical rather than vinyl insertion mechanism appears to be operative.

  DOI：

  10.1021/om050126a